Novel [1,5] Sigmatropic Rearrangements of Cyclohexadienones Generated from Fischer Carbene Complexes. A New Strategy for Installing the C-20 Angular Ethyl Group in Aspidospermidine Alkaloids

John F. Quinn; Mary Ellen Bos; William D. Wulff

doi:10.1021/ol990063q

Novel [1,5] Sigmatropic Rearrangements of Cyclohexadienones Generated from Fischer Carbene Complexes. A New Strategy for Installing the C-20 Angular Ethyl Group in Aspidospermidine Alkaloids

Organic Letters ◽

10.1021/ol990063q ◽

1999 ◽

Vol 1 (1) ◽

pp. 161-164 ◽

Cited By ~ 12

Author(s):

John F. Quinn ◽

Mary Ellen Bos ◽

William D. Wulff

Keyword(s):

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Ethyl Group ◽

Fischer Carbene ◽

Sigmatropic Rearrangements ◽

New Strategy

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ChemInform Abstract: Novel [1,5] Sigmatropic Rearrangements of Cyclohexadienones Generated from Fischer Carbene Complexes. A New Strategy for Installing the C-20 Angular Ethyl Group in Aspidospermidine Alkaloids.

ChemInform ◽

10.1002/chin.199942050 ◽

2010 ◽

Vol 30 (42) ◽

pp. no-no

Author(s):

John F. Quinn ◽

Mary Ellen Bos ◽

William D. Wulff

Keyword(s):

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Ethyl Group ◽

Fischer Carbene ◽

Sigmatropic Rearrangements ◽

New Strategy

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The DFT study on pentannulation reaction of tungsten Fischer carbene complexes

Computational and Theoretical Chemistry ◽

10.1016/j.comptc.2020.113121 ◽

2021 ◽

Vol 1196 ◽

pp. 113121

Author(s):

Mirana C. Angel ◽

Victor L. Prutyanov

Keyword(s):

Dft Study ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene

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ChemInform Abstract: Polycyclic Cyclopropanes from Reactions of Alkene-Containing Fischer Carbene Complexes and Alkynes: A Formal Synthesis of (.+-.)-Carabrone.

ChemInform ◽

10.1002/chin.199547228 ◽

2010 ◽

Vol 26 (47) ◽

pp. no-no

Author(s):

T. R. HOYE ◽

J. R. VYVYAN

Keyword(s):

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Formal Synthesis ◽

Fischer Carbene

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A New Synthesis of Allyl Sulfoxides via Nucleophilic Addition of Sulfinyl Carbanions to Group 6 Fischer Carbene Complexes.

ChemInform ◽

10.1002/chin.200533097 ◽

2005 ◽

Vol 36 (33) ◽

Author(s):

Jose Barluenga ◽

Martin Fananas-Mastral ◽

Fernando Aznar

Keyword(s):

Nucleophilic Addition ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene ◽

New Synthesis ◽

Group 6

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Coupling of Fischer Carbene Complexes with Conjugated Enyne−Aldehydes and Ketones: A Novel Synthesis of Furan Derivatives

The Journal of Organic Chemistry ◽

10.1021/jo9803939 ◽

1998 ◽

Vol 63 (14) ◽

pp. 4564-4565 ◽

Cited By ~ 48

Author(s):

James W. Herndon ◽

Haixia Wang

Keyword(s):

Fischer Carbene Complexes ◽

Furan Derivatives ◽

Carbene Complexes ◽

Fischer Carbene ◽

Novel Synthesis ◽

Aldehydes And Ketones

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ChemInform Abstract: Coupling of Fischer Carbene Complexes with Conjugated Enyne-Aldehydes and Ketones: A Novel Synthesis of Furan Derivatives.

ChemInform ◽

10.1002/chin.199849132 ◽

2010 ◽

Vol 29 (49) ◽

pp. no-no

Author(s):

J. W. HERNDON ◽

H. WANG

Keyword(s):

Fischer Carbene Complexes ◽

Furan Derivatives ◽

Carbene Complexes ◽

Fischer Carbene ◽

Novel Synthesis ◽

Aldehydes And Ketones

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Computational and experimental tools in solving some mechanistic problems in the chemistry of Fischer carbene complexes

Chemical Communications ◽

10.1039/b807806h ◽

2008 ◽

pp. 4671 ◽

Cited By ~ 43

Author(s):

Miguel A. Sierra ◽

Israel Fernández ◽

Fernando P. Cossío

Keyword(s):

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene

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Selective Remote Functionalization of Alkyl Side Chains in the Coupling of Fischer Carbene Complexes with Conjugated Enediynes

Tetrahedron ◽

10.1016/s0040-4020(99)01100-x ◽

2000 ◽

Vol 56 (15) ◽

pp. 2175-2182 ◽

Cited By ~ 22

Author(s):

Yi Zhang ◽

James W. Herndon

Keyword(s):

Side Chains ◽

Fischer Carbene Complexes ◽

Carbene Complexes ◽

Fischer Carbene ◽

Alkyl Side Chains

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Formation of Fischer Carbene Complexes in Asymmetric Aldol-Type Condensation of an Isocyanide Component on Bis(oxazolinyl)phenylrhodium(III) Complexes with Aldehydes: Stereochemistry, Structural Characterization, and Mechanistic Studies

Organometallics ◽

10.1021/om011011j ◽

2002 ◽

Vol 21 (8) ◽

pp. 1684-1696 ◽

Cited By ~ 32

Author(s):

Yukihiro Motoyama ◽

Kayoko Shimozono ◽

Katsuyuki Aoki ◽

Hisao Nishiyama

Keyword(s):

Structural Characterization ◽

Mechanistic Studies ◽

Fischer Carbene Complexes ◽

Asymmetric Aldol ◽

Carbene Complexes ◽

Fischer Carbene

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Amine-Catalyzed Coupling of Aldehydes and Ketenes Derived from Fischer Carbene Complexes: Formation of β-Lactones and Enol Ethers

The Journal of Organic Chemistry ◽

10.1021/jo034476n ◽

2003 ◽

Vol 68 (15) ◽

pp. 6056-6059 ◽

Cited By ~ 20

Author(s):

Craig A. Merlic ◽

Brandon C. Doroh

Keyword(s):

Fischer Carbene Complexes ◽

Enol Ethers ◽

Carbene Complexes ◽

Fischer Carbene

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