Strain-Release Electrophilic Activation viaE-Cycloalkenones

2007 ◽  
Vol 9 (20) ◽  
pp. 3893-3896 ◽  
Author(s):  
Joseph Moran ◽  
Peter Dornan ◽  
André M. Beauchemin
Keyword(s):  
Strain Release ◽  
Electrophilic Activation

ChemInform Abstract: Strain-Release Electrophilic Activation via E-Cycloalkenones.

ChemInform ◽  
2008 ◽  
Vol 39 (11) ◽  
Author(s):  
Joseph Moran ◽  
Peter Dornan ◽  
Andre M. Beauchemin
Keyword(s):  
Strain Release ◽  
Electrophilic Activation

Uncertainty of strain release coefficients for the blind-hole procedure evaluated by Monte Carlo simulation

2017 ◽  
Vol 59 (7-8) ◽  
pp. 630-634 ◽  
Author(s):  
Bin Qiang ◽  
Yadong Li ◽  
Ying Gu ◽  
Dossa Didier Boko-haya
Keyword(s):  
Monte Carlo Simulation ◽  
Monte Carlo ◽  
Blind Hole ◽  
Strain Release

scholarly journals Facile assembly of 1,5-diazocan-2-ones via cyclization of tethered sulfonamides to cyclopropenes

RSC Advances ◽  
2020 ◽  
Vol 10 (72) ◽  
pp. 44183-44190
Author(s):  
Jonathon P. Matheny ◽  
Pavel M. Yamanushkin ◽  
Peter A. Petillo ◽  
Michael Rubin
Keyword(s):  
Nucleophilic Addition ◽  
Functional Group ◽  
Strain Release

The sulfonamide moiety was evaluated as an activating and stabilizing functional group in the metal templated strain release-driven intramolecular nucleophilic addition of amines to cyclopropenes to generate 1,5-diazocan-2-ones.

Electrophilic activation of alkynes for enyne cycloisomerization reactions with in situ generated early/late heterobimetallic Pt–Ti catalysts

2016 ◽  
Vol 45 (24) ◽  
pp. 9770-9773 ◽  
Author(s):  
Michael R. Talley ◽  
Ryjul W. Stokes ◽  
Whitney K. Walker ◽  
David J. Michaelis
Keyword(s):  
Room Temperature ◽  
Electrophilic Activation ◽  
Early Late

In situ assembly of a heterobimetallic Pt–Ti catalyst from a titanium-containing phosphinoamide ligand enables fast room temperature catalysis in enyne cycloisomerization reactions.

scholarly journals Strain‐Release Driven Spirocyclization of Azabicyclo[1.1.0]butyl Ketones

2021 ◽  
Author(s):  
Varinder Kumar Aggarwal ◽  
Jasper Tyler ◽  
Adam Noble
Keyword(s):  
Strain Release

Insights into complicated Au(I)-catalyzed polycycloisomerization driven by strain release: A DFT study

2022 ◽  
Vol 518 ◽  
pp. 112082
Author(s):  
Wenxuan Xin ◽  
Siwei Bi ◽  
Wanying Zhang ◽  
Jingjing Hu ◽  
YuanYe Jiang ◽  
...  
Keyword(s):  
Dft Study ◽  
Strain Release
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