Kinetic Resolution of 2-Substituted 2,3-Dihydro-4-pyridones by Palladium-Catalyzed Asymmetric Allylic Alkylation: Catalytic Asymmetric Total Synthesis of Indolizidine (−)-209I

2014 ◽  
Vol 16 (7) ◽  
pp. 1944-1947 ◽  
Author(s):  
Bai-Lin Lei ◽  
Qing-Song Zhang ◽  
Wei-Hua Yu ◽  
Qiu-Ping Ding ◽  
Chang-Hua Ding ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Kinetic Resolution ◽  
Allylic Alkylation ◽  
Asymmetric Total Synthesis ◽  
Asymmetric Allylic Alkylation ◽  
Palladium Catalyzed ◽  
Catalytic Asymmetric

scholarly journals A catalytic asymmetric total synthesis of (−)-perophoramidine

2015 ◽  
Vol 6 (1) ◽  
pp. 349-353 ◽  
Author(s):  
B. M. Trost ◽  
M. Osipov ◽  
S. Krüger ◽  
Y. Zhang
Keyword(s):  
Total Synthesis ◽  
Allylic Alkylation ◽  
Asymmetric Total Synthesis ◽  
Asymmetric Allylic Alkylation ◽  
Catalytic Asymmetric ◽  
Key Steps

We describe a catalytic asymmetric total synthesis of the ascidian alkaloid (−)-perophoramidine employing a Mo-catalyzed asymmetric allylic alkylation and unprecedented imino ether allylation as key steps.

Total Synthesis of (–)-Strempeliopine via Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation

2021 ◽  
Author(s):  
Yi An ◽  
Mengjuan Wu ◽  
Weijian Li ◽  
Yaling Li ◽  
Zhenzhen Wang ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Enantioselective Total Synthesis ◽  
Synthetic Strategy ◽  
Palladium Catalyzed ◽  
The Absolute ◽  
Set Up

Reported herein a concise and enantioselective total synthesis of Schizozygine alkaloids (–)-strempeliopine. This synthetic strategy features a palladium-catalyzed decarboxylative asymmetric allylic alkylation of N-benzoyl lactam to set up the absolute...

Dynamic Kinetic Resolution for the Catalytic Asymmetric Total Synthesis of Antithrombotic Agents M58163 and M58169

2007 ◽  
Vol 349 (4-5) ◽  
pp. 617-628 ◽  
Author(s):  
Fumihiko Saitoh ◽  
Hidemitsu Nishida ◽  
Takafumi Mukaihira ◽  
Kohsuke Aikawa ◽  
Koichi Mikami
Keyword(s):  
Total Synthesis ◽  
Kinetic Resolution ◽  
Dynamic Kinetic Resolution ◽  
Antithrombotic Agents ◽  
Asymmetric Total Synthesis ◽  
Catalytic Asymmetric

Kinetic resolution of primary allylic amines via palladium-catalyzed asymmetric allylic alkylation of malononitriles

2015 ◽  
Vol 13 (19) ◽  
pp. 5367-5371 ◽  
Author(s):  
Yong Wang ◽  
Ya-Nan Xu ◽  
Guo-Sheng Fang ◽  
Hong-Jian Kang ◽  
Yonghong Gu ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Bond Cleavage ◽  
Allylic Alkylation ◽  
Allylic Amines ◽  
Asymmetric Allylic Alkylation ◽  
New Strategy ◽  
Palladium Catalyzed

A new strategy has been developed for the catalytic kinetic resolution of primary allylic amines via enantioselective C–N bond cleavage.

Kinetic Resolution of 2,3-Dihydro-2-substituted 4-Quinolones by Palladium-Catalyzed Asymmetric Allylic Alkylation

2009 ◽  
Vol 131 (51) ◽  
pp. 18250-18251 ◽  
Author(s):  
Bai-Lin Lei ◽  
Chang-Hua Ding ◽  
Xiao-Fei Yang ◽  
Xiao-Long Wan ◽  
Xue-Long Hou
Keyword(s):  
Kinetic Resolution ◽  
Allylic Alkylation ◽  
Asymmetric Allylic Alkylation ◽  
Palladium Catalyzed
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