Effect of High Pressure on the Organocatalytic Asymmetric Michael Reaction: Highly Enantioselective Synthesis of γ-Nitroketones with Quaternary Stereogenic Centers

2011 ◽  
Vol 13 (14) ◽  
pp. 3624-3627 ◽  
Author(s):  
Piotr Kwiatkowski ◽  
Krzysztof Dudziński ◽  
Dawid Łyżwa
Keyword(s):  
High Pressure ◽  
Michael Reaction ◽  
Enantioselective Synthesis ◽  
Stereogenic Centers ◽  
Asymmetric Michael Reaction ◽  
Quaternary Stereogenic Centers

scholarly journals Enantioselective synthesis of gem-diarylalkanes by transition metal-catalyzed asymmetric arylations (TMCAAr)

2018 ◽  
Vol 9 (3) ◽  
pp. 546-559 ◽  
Author(s):  
Tao Jia ◽  
Peng Cao ◽  
Jian Liao
Keyword(s):  
Transition Metal ◽  
Enantioselective Synthesis ◽  
Transfer Reactions ◽  
Stereogenic Centers ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Quaternary Stereogenic Centers ◽  
Aryl Transfer

To date, enantiomerically enriched molecules containing gem(1,1)-diaryl containing tertiary or quaternary stereogenic centers have been readily accessed by transition metal-catalyzed enantioselective or stereoconvergent aryl transfer reactions.

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