Asymmetric Synthesis of α-Keto Esters via Cu(II)-Catalyzed Aerobic Deacylation of Acetoacetate Alkylation Products: An Unusually Simple Synthetic Equivalent to the Glyoxylate Anion Synthon

Kimberly M. Steward; Jeffrey S. Johnson

doi:10.1021/ol201245p

Asymmetric Synthesis of α-Keto Esters via Cu(II)-Catalyzed Aerobic Deacylation of Acetoacetate Alkylation Products: An Unusually Simple Synthetic Equivalent to the Glyoxylate Anion Synthon

Organic Letters ◽

10.1021/ol201245p ◽

2011 ◽

Vol 13 (11) ◽

pp. 2975-2975

Author(s):

Kimberly M. Steward ◽

Jeffrey S. Johnson

Keyword(s):

Asymmetric Synthesis ◽

Keto Esters ◽

Synthetic Equivalent

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Asymmetric Synthesis of α-Keto Esters via Cu(II)-Catalyzed Aerobic Deacylation of Acetoacetate Alkylation Products: An Unusually Simple Synthetic Equivalent to the Glyoxylate Anion Synthon

Organic Letters ◽

10.1021/ol200649u ◽

2011 ◽

Vol 13 (9) ◽

pp. 2426-2429 ◽

Cited By ~ 29

Author(s):

Kimberly M. Steward ◽

Jeffrey S. Johnson

Keyword(s):

Asymmetric Synthesis ◽

Keto Esters ◽

Synthetic Equivalent

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711. Partial asymmetric synthesis with keto-esters. Part III

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9510003227 ◽

1951 ◽

pp. 3227 ◽

Cited By ~ 2

Author(s):

Doreen M. Bovey ◽

Joan A. Reid ◽

E. E. Turner

Keyword(s):

Asymmetric Synthesis ◽

Keto Esters

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ChemInform Abstract: Asymmetric Synthesis of anti-β-Amino-α-hydroxy Esters via Dynamic Kinetic Resolution of β-Amino-α-keto Esters.

ChemInform ◽

10.1002/chin.201336066 ◽

2013 ◽

Vol 44 (36) ◽

pp. no-no

Author(s):

C. Guy Goodman ◽

Dung T. Do ◽

Jeffrey S. Johnson

Keyword(s):

Asymmetric Synthesis ◽

Kinetic Resolution ◽

Dynamic Kinetic Resolution ◽

Keto Esters ◽

Hydroxy Esters

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Asymmetric Synthesis of Diverse Glycolic Acid Scaffolds via Dynamic Kinetic Resolution of α-Keto Esters

Journal of the American Chemical Society ◽

10.1021/ja3102709 ◽

2012 ◽

Vol 134 (49) ◽

pp. 20197-20206 ◽

Cited By ~ 53

Author(s):

Kimberly M. Steward ◽

Michael T. Corbett ◽

C. Guy Goodman ◽

Jeffrey S. Johnson

Keyword(s):

Asymmetric Synthesis ◽

Glycolic Acid ◽

Kinetic Resolution ◽

Dynamic Kinetic Resolution ◽

Keto Esters

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709. Partial asymmetric synthesis with keto-esters. Part I

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9510003219 ◽

1951 ◽

pp. 3219 ◽

Cited By ~ 4

Author(s):

Joan A. Reid ◽

E. E. Turner

Keyword(s):

Asymmetric Synthesis ◽

Keto Esters

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Asymmetric synthesis of chiral α-keto esters via Grignard addition to oxalates

Tetrahedron Asymmetry ◽

10.1016/j.tetasy.2003.08.013 ◽

2003 ◽

Vol 14 (20) ◽

pp. 3177-3181 ◽

Cited By ~ 4

Author(s):

David I. MaGee ◽

Tammy C. Mallais ◽

Marijanna Eic

Keyword(s):

Asymmetric Synthesis ◽

Keto Esters ◽

Grignard Addition

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ChemInform Abstract: ASYMMETRIC SYNTHESIS OF β-SUBSTITUTED Δ-KETO ESTERS VIA MICHAEL ADDITIONS OF (S)-AMP/(R)-AMP HYDRAZONES (AMP = 1-AMINO-2-METHOXYMETHYLPYRROLIDINE) TO α,β-UNSATURATED ESTERS. VIRTUALLY COMPLETE 1,6-ASYMMETRIC INDUCTION

Chemischer Informationsdienst ◽

10.1002/chin.198409179 ◽

1984 ◽

Vol 15 (9) ◽

Author(s):

D. ENDERS ◽

K. PAPADOPOULOS

Keyword(s):

Asymmetric Synthesis ◽

Asymmetric Induction ◽

Unsaturated Esters ◽

Keto Esters ◽

Michael Additions

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ChemInform Abstract: α-(Arylsulfonamido)borneols as Auxiliaries in Asymmetric Synthesis: An Efficient and Highly Stereoselective Method for the Reduction of α-Keto Esters.

ChemInform ◽

10.1002/chin.199322092 ◽

2010 ◽

Vol 24 (22) ◽

pp. no-no

Author(s):

Y. B. XIANG ◽

K. SNOW ◽

M. BELLEY

Keyword(s):

Asymmetric Synthesis ◽

Keto Esters ◽

Stereoselective Method

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Asymmetric synthesis using C2-symmetric diols: Use of (5R,6R)-3-acetoxy-5,6-diphenyl-1,4-dioxan-2-one as a chiral synthetic equivalent of 1,2-ethanediol 1,2-dicarbocation

Tetrahedron Asymmetry ◽

10.1016/0957-4166(95)00278-w ◽

1995 ◽

Vol 6 (9) ◽

pp. 2117-2120 ◽

Cited By ~ 16

Author(s):

Hiromichi Fujioka ◽

Naoki Matsunaga ◽

Hidetoshi Kitagawa ◽

Yasushi Nagatomi ◽

Michinori Kondo ◽

...

Keyword(s):

Asymmetric Synthesis ◽

Synthetic Equivalent

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Correction to “Asymmetric Synthesis of Diverse Glycolic Acid Scaffolds via Dynamic Kinetic Resolution of α-Keto Esters”

Journal of the American Chemical Society ◽

10.1021/jacs.5b02204 ◽

2015 ◽

Vol 137 (11) ◽

pp. 3991-3991 ◽

Cited By ~ 1

Author(s):

Kimberly M. Steward ◽

Michael T. Corbett ◽

C. Guy Goodman ◽

Jeffrey S. Johnson

Keyword(s):

Asymmetric Synthesis ◽

Glycolic Acid ◽

Kinetic Resolution ◽

Dynamic Kinetic Resolution ◽

Keto Esters

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