Inhibition of (+)-Aristolochene Synthase with Iminium Salts Resembling Eudesmane Cation

Juan A. Faraldos; Rudolf K. Allemann

doi:10.1021/ol2000843

Inhibition of (+)-Aristolochene Synthase with Iminium Salts Resembling Eudesmane Cation

Organic Letters ◽

10.1021/ol2000843 ◽

2011 ◽

Vol 13 (5) ◽

pp. 1202-1205 ◽

Cited By ~ 18

Author(s):

Juan A. Faraldos ◽

Rudolf K. Allemann

Keyword(s):

Iminium Salts ◽

Aristolochene Synthase

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Faculty Opinions recommendation of Formation of a Novel Macrocyclic Alkaloid from the Unnatural Farnesyl Diphosphate Analogue Anilinogeranyl Diphosphate by 5-Epi-Aristolochene Synthase.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.725442771.793512383 ◽

2015 ◽

Author(s):

Jon Thorson

Keyword(s):

Farnesyl Diphosphate ◽

Aristolochene Synthase

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A new protocol for the Baylis–Hillman reaction: the reaction of iminium salts prepared in situ with methyl acrylate

Tetrahedron Letters ◽

10.1016/s0040-4039(02)00803-1 ◽

2002 ◽

Vol 43 (24) ◽

pp. 4305-4308 ◽

Cited By ~ 24

Author(s):

Najmedin Azizi ◽

Mohammad R Saidi

Keyword(s):

Methyl Acrylate ◽

Iminium Salts

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Alkoxycarbonyl-Substituted 3-Trifloxypropene Iminium Salts and Iminium-Substituted Δ2,3-Butenolides: Synthesis and Reactivity toward Nucleophiles

Synthesis ◽

10.1055/s-2003-42440 ◽

2003 ◽

pp. 2679-2688 ◽

Cited By ~ 1

Author(s):

Gerhard Maas ◽

Joachim Nikolai

Keyword(s):

Iminium Salts

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Evidence for Differential Folding of Farnesyl Pyrophosphate in the Active Site of Aristolochene Synthase: A Single-Point Mutation Converts Aristolochene Synthase into an (E)-β-Farnesene Synthase†

Biochemistry ◽

10.1021/bi034410m ◽

2003 ◽

Vol 42 (25) ◽

pp. 7741-7747 ◽

Cited By ~ 44

Author(s):

Athina Deligeorgopoulou ◽

Rudolf K. Allemann

Keyword(s):

Point Mutation ◽

Active Site ◽

Single Point ◽

Single Point Mutation ◽

Farnesyl Pyrophosphate ◽

Aristolochene Synthase

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ChemInform Abstract: Photoisomerization of Some N-Aryl α,β-Unsaturated Iminium Salts.

ChemInform ◽

10.1002/chin.198851096 ◽

1988 ◽

Vol 19 (51) ◽

Author(s):

M. PANKRATZ ◽

R. F. CHILDS

Keyword(s):

Iminium Salts

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Les oxazolines-4 précurseurs de sels d'iminium fonctionnels. Ouverture en milieu anhydre de ces hétérocycles par des acides protoniques: obtention de sels d'iminium fonctionnels, étude de leur structure

Canadian Journal of Chemistry ◽

10.1139/v79-467 ◽

1979 ◽

Vol 57 (21) ◽

pp. 2876-2884 ◽

Cited By ~ 3

Author(s):

Michel Vaultier ◽

Gurbachan Mullick ◽

Robert Carrié

Keyword(s):

Hydrogen Atom ◽

Room Temperature ◽

Iminium Salts ◽

C Nmr

The protonation of 4-oxazolines with protic acids in anhydrous medium, both at low or at room temperature, generally leads to acyclic functional iminium salts. In those cases where the oxazoline ring bears a hydrogen atom in the four position, two diastereoisomeric cyclic iminium salts are obtained. The conditions for preparation of these salts along with the characterization of their structures were determined by the aid of 1H and 13C nmr.

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