Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Esters with Aldehydes

2011 ◽  
Vol 13 (4) ◽  
pp. 592-595 ◽  
Author(s):  
Akiko Yoshida ◽  
Masahiro Ikeda ◽  
Gaku Hattori ◽  
Yoshihiro Miyake ◽  
Yoshiaki Nishibayashi
Keyword(s):  
Transition Metal ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Catalytic Reactions ◽  
Propargylic Esters

Topological aspects of chemical reactivity. Catalytic reactions

1986 ◽  
Vol 51 (9) ◽  
pp. 1843-1855 ◽  
Author(s):  
Robert Ponec
Keyword(s):  
Transition Metal ◽  
Detailed Analysis ◽  
Chemical Reactivity ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Catalytic Reactions ◽  
Pericyclic Reactions

Recently proposed overlap determinant method is applied to the description of reactions induced by the presence of the transition metal catalysts. The use of this technique is demonstrated on a detailed analysis of a number of examples of thermally forbidden pericyclic reactions in which the interaction with the catalyst removes the symmetry restrictions imposed by Woodward-Hoffmann rules.

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