Formation of Chiral Quaternary Carbon Stereocenters Using Silylene Transfer Reactions:  Enantioselective Synthesis of (+)-5-epi-Acetomycin

2007 ◽  
Vol 9 (6) ◽  
pp. 1037-1040 ◽  
Author(s):  
Stacie A. Calad ◽  
K. A. Woerpel
Keyword(s):  
Enantioselective Synthesis ◽  
Transfer Reactions ◽  
Quaternary Carbon ◽  
Silylene Transfer

Regio‐ and Enantioselective Synthesis of Sulfone‐Bearing Quaternary Carbon Stereocenters by Pd‐Catalyzed Allylic Substitution

2019 ◽  
Vol 132 (3) ◽  
pp. 1356-1361 ◽  
Author(s):  
Ajmal Khan ◽  
Heng Zhao ◽  
Meina Zhang ◽  
Shahid Khan ◽  
Depeng Zhao
Keyword(s):  
Enantioselective Synthesis ◽  
Allylic Substitution ◽  
Quaternary Carbon

scholarly journals Enantioselective synthesis of gem-diarylalkanes by transition metal-catalyzed asymmetric arylations (TMCAAr)

2018 ◽  
Vol 9 (3) ◽  
pp. 546-559 ◽  
Author(s):  
Tao Jia ◽  
Peng Cao ◽  
Jian Liao
Keyword(s):  
Transition Metal ◽  
Enantioselective Synthesis ◽  
Transfer Reactions ◽  
Stereogenic Centers ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Quaternary Stereogenic Centers ◽  
Aryl Transfer

To date, enantiomerically enriched molecules containing gem(1,1)-diaryl containing tertiary or quaternary stereogenic centers have been readily accessed by transition metal-catalyzed enantioselective or stereoconvergent aryl transfer reactions.

Silylene-transfer reactions of cyclic organosilanes induced by phenanthraquinone triplet

2001 ◽  
Vol 636 (1-2) ◽  
pp. 63-68 ◽  
Author(s):  
Masahiro Kako ◽  
Masumi Ninomiya ◽  
Mei Gu ◽  
Yasuhiro Nakadaira ◽  
Masanobu Wakasa ◽  
...  
Keyword(s):  
Transfer Reactions ◽  
Silylene Transfer
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