Asymmetric Nitroallylation of Arylboronic Acids with Nitroallyl Acetates Catalyzed by Chiral Rhodium Complexes and Its Application in a Concise Total Synthesis of Optically Pure (+)-γ-Lycorane

2005 ◽  
Vol 7 (19) ◽  
pp. 4285-4288 ◽  
Author(s):  
Lin Dong ◽  
Yan-Jun Xu ◽  
Lin-Feng Cun ◽  
Xin Cui ◽  
Ai-Qiao Mi ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Rhodium Complexes ◽  
Arylboronic Acids ◽  
Optically Pure

scholarly journals Expedient Access to Enantiopure Cyclopentanic Natural Products: Total Synthesis of (-)-Cyclonerodiol

2015 ◽  
Vol 10 (1) ◽  
pp. 1934578X1501000
Author(s):  
Carmen Pérez Morales ◽  
M. Mar Herrador ◽  
José F. Quílez del Moral ◽  
Alejandro F. Barrero
Keyword(s):  
Natural Products ◽  
Total Synthesis ◽  
Radical Cyclization ◽  
Formal Synthesis ◽  
Common Precursor ◽  
Enantiospecific Synthesis ◽  
Optically Pure

Following the principles of collective total synthesis, a number of natural products sharing an optically pure, multifunctional, cyclopentanic core were synthesized from a common precursor: plinol A (1). This intermediate was efficiently obtained in only four steps from (-)-linalool (2) using as the key step a Ti(III)-mediated diastereoselective radical cyclization. The feasibility of this approach was confirmed with the expedient enantiospecific synthesis of cyclonerodiol (3), and the formal synthesis of chocol G (4) and piperitone (5).

Heterocycles. XXVI. A total synthesis of optically pure (+)-catechin pentaacetate

1991 ◽  
Vol 28 (8) ◽  
pp. 1845-1847 ◽  
Author(s):  
Mieko Urano ◽  
Hitoshi Kagawa ◽  
Yoshihiro Harigaya ◽  
Shaoshun Li ◽  
Masayuki Onda
Keyword(s):  
Total Synthesis ◽  
Optically Pure

First total synthesis of optically pure deoxyschizandrin and wuweizisu C. The thermal stability of biaryl configuration

1994 ◽  
Vol 35 (22) ◽  
pp. 3733-3736 ◽  
Author(s):  
Masahide Tanaka ◽  
Hiroshi Mitsuhashi ◽  
Masao Maruno ◽  
Takeshi Wakamatsu
Keyword(s):  
Thermal Stability ◽  
Total Synthesis ◽  
Optically Pure ◽  
Thermal Stability Of
Sign in / Sign up

Export Citation Format

Share Document