A New and Efficient Method foro-Quinone Methide Intermediate Generation:  Application to the Biomimetic Synthesis of (±)-Alboatrin

2004 ◽  
Vol 6 (20) ◽  
pp. 3617-3619 ◽  
Author(s):  
Raphaël Rodriguez ◽  
Robert M. Adlington ◽  
John E. Moses ◽  
Andrew Cowley ◽  
Jack E. Baldwin
Keyword(s):  
Efficient Method ◽  
Biomimetic Synthesis ◽  
Quinone Methide

scholarly journals A New and Efficient Method for o-Quinone Methide Intermediate Generation: Application to the Biomimetic Synthesis of (.+-.)-Alboatrin.

ChemInform ◽  
2005 ◽  
Vol 36 (4) ◽  
Author(s):  
Raphael Rodriguez ◽  
Robert M. Adlington ◽  
John E. Moses ◽  
Andrew Cowley ◽  
Jack E. Baldwin
Keyword(s):  
Efficient Method ◽  
Biomimetic Synthesis ◽  
Quinone Methide

scholarly journals A Biomimetic Synthesis of des-Hydroxy Paecilospirone

Synlett ◽  
2018 ◽  
Vol 29 (11) ◽  
pp. 1517-1519 ◽  
Author(s):  
Thomas Pettus ◽  
Zhen-Gao Feng ◽  
G. Burnett
Keyword(s):  
Carbon Skeleton ◽  
Biomimetic Synthesis ◽  
Quinone Methide ◽  
Enol Ether ◽  
Carbon Framework ◽  
Biomimetic Approach

The carbon framework of des-hydroxy paecilospirone was rapidly synthesized using a biomimetic approach whereby an enol ether and an ortho-quinone methide (o-QM), each derived from the same lactone, were combined to arrive at the complete carbon skeleton of paecilospirone.

Iron-catalysed asymmetric tandem spiro-cyclization using dioxygen in air as the hydrogen acceptor

2014 ◽  
Vol 50 (39) ◽  
pp. 5053-5056 ◽  
Author(s):  
Takuya Oguma ◽  
Tsutomu Katsuki
Keyword(s):  
Efficient Method ◽  
Michael Addition ◽  
Quinone Methide ◽  
Hydrogen Acceptor

A tandem combination of ortho-quinone methide (o-QM) formation/Michael addition/asymmetric dearomatization, which is catalysed by an iron–salan complex in air with high enantioselectivity, provides an efficient method for spirocyclic (2H)-dihydrobenzofuran synthesis from 2-naphthols and phenols.

Sign in / Sign up

Export Citation Format

Share Document