3,3‘-Br2-BINOL-Zn Complex:  A Highly Efficient Catalyst for the Enantioselective Hetero-Diels−Alder Reaction

2002 ◽  
Vol 4 (24) ◽  
pp. 4349-4352 ◽  
Author(s):  
Haifeng Du ◽  
Jiang Long ◽  
Jieyu Hu ◽  
Xin Li ◽  
Kuiling Ding
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Efficient Catalyst ◽  
Highly Efficient ◽  
Diels Alder Reaction

scholarly journals 3,3′-Br2-BINOL-Zn Complex: A Highly Efficient Catalyst for the Enantioselective Hetero-Diels—Alder Reaction.

ChemInform ◽  
2003 ◽  
Vol 34 (16) ◽  
Author(s):  
Haifeng Du ◽  
Jiang Long ◽  
Jieyu Hu ◽  
Xin Li ◽  
Kuiling Ding
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Efficient Catalyst ◽  
Highly Efficient ◽  
Diels Alder Reaction

Chiral Cationic Pd-Phosphinooxazolidine Catalysts for a Highly Efficient Asymmetric Diels-Alder Reaction in Ionic Liquids

Heterocycles ◽  
2008 ◽  
Vol 76 (1) ◽  
pp. 381 ◽  
Author(s):  
Hiroto Nakano ◽  
Mitsuhiro Takeshita ◽  
Yasuhiro Nishiuchi ◽  
Kouichi Takahashi ◽  
Reiko Fujita ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Alder Reaction ◽  
Diels Alder ◽  
Highly Efficient ◽  
Diels Alder Reaction

scholarly journals Combination of inverse electron-demand Diels–Alder reaction with highly efficient oxime ligation expands the toolbox of site-selective peptide conjugations

2015 ◽  
Vol 51 (55) ◽  
pp. 11130-11133 ◽  
Author(s):  
S. Hörner ◽  
C. Uth ◽  
O. Avrutina ◽  
H. Frauendorf ◽  
M. Wiessler ◽  
...  
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Inverse Electron Demand ◽  
Highly Efficient ◽  
Diels Alder Reaction ◽  
Site Selective ◽  
Electron Demand

A modular bioconjugation strategy based on stepwise oxime ligation and inverse electron-demand Diels–Alder reaction.

Copper(i)/TF-BiphamPhos catalyzed asymmetric nitroso Diels–Alder reaction

2017 ◽  
Vol 53 (10) ◽  
pp. 1657-1659 ◽  
Author(s):  
Jun Li ◽  
Hai-Yan Tao ◽  
Chun-Jiang Wang
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Highly Efficient ◽  
Diels Alder Reaction ◽  
Cyclic Dienes ◽  
High Yields

A highly efficient enantioselective nitroso Diels–Alder reaction of 6-methyl-2-nitroso pyridine with various 1,3-dienes was successfully developed using a copper(i)/(S)–TF-BiphamPhos complex as the catalyst. For most of the cyclic dienes, the cycloadducts were obtained in high yields with excellent regio-, and stereoselectivities. Acyclic 2-silyloxy-1,3-diene also worked well in the reaction.

A Flow Microreactor Approach to a Highly Efficient Diels–Alder Reaction with an Electrogenerated o-Quinone

Synlett ◽  
2019 ◽  
Vol 30 (10) ◽  
pp. 1194-1198 ◽  
Author(s):  
Kenta Tanaka ◽  
Hirona Yoshizawa ◽  
Mahito Atobe
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Tert Butyl ◽  
Highly Efficient ◽  
Diels Alder Reaction ◽  
Flow Microreactor ◽  
Chemical Oxidants

We have demonstrated a Diels–Alder reaction of an o-quinone generated in an electrochemical flow microreactor. In the flow microreactor system, 4-tert-butyl-o-benzoquinone was easily electrogenerated from 4-tert-butylpyrocatechol in the absence of chemical oxidants and then rapidly used, without decomposing, in a subsequent Diels–Adler reaction with various fulvenes to give the desired products efficiently.

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