Tetrabutylammonium Tribromide (TBATB)−MeOH:  An Efficient Chemoselective Reagent for the Cleavage oftert-Butyldimethylsilyl (TBDMS) Ethers

Rangam Gopinath; Bhisma K. Patel

doi:10.1021/ol006720s

Tetrabutylammonium Tribromide (TBATB)−MeOH: An Efficient Chemoselective Reagent for the Cleavage oftert-Butyldimethylsilyl (TBDMS) Ethers

Organic Letters ◽

10.1021/ol006720s ◽

2000 ◽

Vol 2 (26) ◽

pp. 4177-4180 ◽

Cited By ~ 58

Author(s):

Rangam Gopinath ◽

Bhisma K. Patel

Keyword(s):

Tetrabutylammonium Tribromide

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Tetrabutylammonium tribromide: an effective green reagent for the one-pot reaction of 3-acetyl-2H-chromen-2-ones with o-phenylenediamines

ARKIVOC ◽

10.24820/ark.5550190.p010.655 ◽

2018 ◽

Vol 2018 (7) ◽

pp. 172-185 ◽

Cited By ~ 5

Author(s):

Kotthireddy Kavitha ◽

Devulapally Srikrishna ◽

Pramod Kumar Dubey ◽

Pasula Aparna

Keyword(s):

One Pot ◽

Tetrabutylammonium Tribromide ◽

The One

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Regioselective Monobromination of Aromatic Amines with Tetrabutylammonium Tribromide

Synthetic Communications ◽

10.1080/00397918608056422 ◽

1986 ◽

Vol 16 (13) ◽

pp. 1641-1645 ◽

Cited By ~ 42

Author(s):

J. Berthelot ◽

C. Guette ◽

M. Essayegh ◽

P. L. Desbene ◽

J. J. Basselier

Keyword(s):

Aromatic Amines ◽

Tetrabutylammonium Tribromide

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An environmentally benign synthesis of aurones and flavones from 2′-acetoxychalcones using n -tetrabutylammonium tribromide

Tetrahedron Letters ◽

10.1016/s0040-4039(01)01938-4 ◽

2001 ◽

Vol 42 (50) ◽

pp. 8907-8909 ◽

Cited By ~ 54

Author(s):

Gopal Bose ◽

Ejabul Mondal ◽

Abu T Khan ◽

Manob J Bordoloi

Keyword(s):

Environmentally Benign ◽

Tetrabutylammonium Tribromide ◽

Benign Synthesis

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Use of tetrabutylammonium tribromide for voltametric titration of unsaturation in vegetable oils and fatty acids

Journal of the American Oil Chemists Society ◽

10.1007/bf02545308 ◽

1993 ◽

Vol 70 (3) ◽

pp. 277-279

Author(s):

J. Berthelot ◽

P-L. Desbène ◽

A. Desbène-Monvernay

Keyword(s):

Fatty Acids ◽

Vegetable Oils ◽

Tetrabutylammonium Tribromide

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Kinetics and mechanism of the oxidation of some neutral and acidic α-amino acids by tetrabutylammonium tribromide

Journal of Chemical Sciences ◽

10.1007/bf02708202 ◽

2004 ◽

Vol 116 (2) ◽

pp. 101-106 ◽

Cited By ~ 8

Author(s):

Raghvendra Shukla ◽

Pradeep K. Sharma ◽

Kalyan K. Banerji

Keyword(s):

Amino Acids ◽

Kinetics And Mechanism ◽

Tetrabutylammonium Tribromide

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Kinetics and Mechanism of Oxidation of Hydroquinone by Tetrabutylammonium Tribromide Ion in Aqueous Acetic Acid

Journal of Solution Chemistry ◽

10.1007/s10953-010-9567-0 ◽

2010 ◽

Vol 39 (8) ◽

pp. 1178-1186

Author(s):

S. N. Zende ◽

V. A. Kalantre ◽

G. S. Gokavi

Keyword(s):

Acetic Acid ◽

Kinetics And Mechanism ◽

Aqueous Acetic Acid ◽

Tetrabutylammonium Tribromide ◽

Mechanism Of Oxidation

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Tetrabutylammonium tribromide

Fieser and Fieser's Reagents for Organic Synthesis ◽

10.1002/9780471264194.fos09528 ◽

2006 ◽

Author(s):

Tse-Lok Ho ◽

Mary Fieser ◽

Janice Smith ◽

Louis Fieser

Keyword(s):

Tetrabutylammonium Tribromide

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ChemInform Abstract: Regioselective Monobromination of Aromatic Amines with Tetrabutylammonium Tribromide.

ChemInform ◽

10.1002/chin.198718100 ◽

1987 ◽

Vol 18 (18) ◽

Author(s):

J. BERTHELOT ◽

C. GUETTE ◽

M. ESSAYEGH ◽

P. L. DESBENE ◽

J. J. BASSELIER

Keyword(s):

Aromatic Amines ◽

Tetrabutylammonium Tribromide

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Synthesis of highly functionalized piperidines by one-pot multicomponent reaction using tetrabutylammonium tribromide (TBATB)

Tetrahedron Letters ◽

10.1016/j.tetlet.2010.06.069 ◽

2010 ◽

Vol 51 (33) ◽

pp. 4419-4424 ◽

Cited By ~ 106

Author(s):

Abu T. Khan ◽

Mohan Lal ◽

Md. Musawwer Khan

Keyword(s):

Multicomponent Reaction ◽

One Pot ◽

Tetrabutylammonium Tribromide

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Action of tetrabutylammonium tribromide with para-substituted chalcones in protic and aprotic media

Canadian Journal of Chemistry ◽

10.1139/v95-189 ◽

1995 ◽

Vol 73 (9) ◽

pp. 1526-1530 ◽

Cited By ~ 6

Author(s):

Jacques Berthelot ◽

Yamina Benammar ◽

Bernard Desmazières

Keyword(s):

Double Bond ◽

Main Reaction ◽

Aprotic Solvents ◽

Mild Conditions ◽

Tetrabutylammonium Tribromide ◽

High Yields

Bromination of the double bond of para-substituted chalcones under mild conditions in aprotic solvents is accomplished with high yields using tetrabutylammonium tribromide (TBABr3). In methanol, the main reaction is (α-β) bromomethoxylation. Stereoselectivity, regioselectivity, and chemioselectivity of this bromomethoxylation reaction are described. Keywords: bromination, bromomethoxylation, tetrabutylammonium tribromide, (α-β) dibromodihydrochalcones, α-bromo, β-methoxydihydrochalcones.

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