Site Specificity in the Photooxidation of Some Trisubstituted Alkenes in Thionin-Supported Zeolite Na−Y. On the Role of the Alkali Metal Cation

2000 ◽  
Vol 2 (10) ◽  
pp. 1369-1372 ◽  
Author(s):  
Manolis Stratakis ◽  
George Froudakis
Keyword(s):  
Alkali Metal ◽  
Metal Cation ◽  
Alkali Metal Cation ◽  
Site Specificity ◽  
Trisubstituted Alkenes

Role of the Alkali-Metal Cation Size in the Self-Assembly of Polyoxometalate-Monolayer Shells on Gold Nanoparticles

2012 ◽  
Vol 51 (14) ◽  
pp. 7436-7438 ◽  
Author(s):  
Yifeng Wang ◽  
Offer Zeiri ◽  
Shelly Sharet ◽  
Ira A. Weinstock
Keyword(s):  
Gold Nanoparticles ◽  
Alkali Metal ◽  
Metal Cation ◽  
Self Assembly ◽  
Alkali Metal Cation ◽  
The Self ◽  
Cation Size

Study of photocatalytic reaction of methanol with water over Rh-, and Pd-loaded TiO2 catalysts. The role of added alkali metal cations

1986 ◽  
Vol 64 (9) ◽  
pp. 1795-1799 ◽  
Author(s):  
Shuichi Naito
Keyword(s):  
Alkali Metal ◽  
Metal Cation ◽  
Methyl Formate ◽  
Alkali Metal Cation ◽  
Metal Cations ◽  
Photocatalytic Reaction ◽  
Product Selectivity ◽  
Alkali Metal Cations ◽  
Selectivity Change

The product selectivity of the photocatalytic reaction of methanol with water is changed drastically by the addition of alkali metal cations to Rh- and Pd-loaded TiO2 catalysts. Over alkali metal cation free catalysts, the main products are 1:1 ratio of H2 and dimethoxymethane, which is replaced with H2, methyl formate, and CO2 over alkali metal cation added catalysts. The role of added alkali metal cations is the stabilization of the reaction intermediate as adsorbed formate instead of adsorbed formaldehyde, which causes the selectivity change from dimethoxymethane to methyl formate.

Conformational effect on the preferential binding of alkali metal cation with crown ether: A molecular level investigation

2009 ◽  
Vol 12 (1-3) ◽  
pp. 93-99 ◽  
Author(s):  
Sulagna De ◽  
Sk. Musharaf Ali ◽  
M.R.K. Shenoi ◽  
Sandip K. Ghosh ◽  
Dilip K. Maity
Keyword(s):  
Crown Ether ◽  
Alkali Metal ◽  
Metal Cation ◽  
Molecular Level ◽  
Alkali Metal Cation ◽  
Conformational Effect ◽  
Preferential Binding

Dynamic chiral-at-metal stability of tetrakis(d/l-hfc)Ln(iii) complexes capped with an alkali metal cation in solution

2012 ◽  
Vol 41 (22) ◽  
pp. 6696 ◽  
Author(s):  
Yiji Lin ◽  
Fang Zou ◽  
Shigang Wan ◽  
Jie Ouyang ◽  
Lirong Lin ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Metal Cation ◽  
Alkali Metal Cation
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