Role of Surfactants and Salt in Aqueous Two-Phase Separation of Carbon Nanotubes toward Simple Chirality Isolation

ACS Nano ◽  
2014 ◽  
Vol 8 (2) ◽  
pp. 1619-1628 ◽  
Author(s):  
Navaneetha K. Subbaiyan ◽  
Sofie Cambré ◽  
A. Nicholas G. Parra-Vasquez ◽  
Erik H. Hároz ◽  
Stephen K. Doorn ◽  
...  
2016 ◽  
Vol 27 (33) ◽  
pp. 332002 ◽  
Author(s):  
Malcolm S Y Tang ◽  
Eng-Poh Ng ◽  
Joon Ching Juan ◽  
Chien Wei Ooi ◽  
Tau Chuan Ling ◽  
...  

2016 ◽  
Vol 18 (33) ◽  
pp. 23383-23388 ◽  
Author(s):  
Yoshinori Tanaka ◽  
Minoru Ikeda ◽  
Masato Sumita ◽  
Takahisa Ohno ◽  
Kazunori Takada

The practical anode material Li4+3xTi5O12 is known to undergo a two-phase separation into Li7Ti5O12 and Li4Ti5O12 during charging/discharging.


The molecular field theory of multicomponent liquid crystalline mixtures, developed by Humphries, James & Luckhurst, has been extended to investigate the possibility of phase separation in binary mixtures of rods and spheres. This extension indicates that the addition of a spherical solute to a liquid crystal depresses the transition from the isotropic to the nematic phase. The solute induced phase transition is first order, although the nematic and isotropic phases are found to be separated by a two-phase region consisting of both nematic and isotropic phases. These qualitative conclusions of the theory are in complete accord with experiment and there is also reasonable agreement with certain quantitative predictions. The same problem has been tackled using a lattice model with purely repulsive anisotropic interactions; this theory would appear to be marginally less successful than our own which is based on a weaker anisotropic potential. Consequently it is not possible to use experimental studies of phase separation in binary liquid crystal mixtures to demonstrate the rôle of repulsive forces in liquid crystal formation.


Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3808 ◽  
Author(s):  
Blazej Podlesny ◽  
Bogumila Kumanek ◽  
Angana Borah ◽  
Ryohei Yamaguchi ◽  
Tomohiro Shiraki ◽  
...  

Single-walled carbon nanotubes (SWCNTs) remain one of the most promising materials of our times. One of the goals is to implement semiconducting and metallic SWCNTs in photonics and microelectronics, respectively. In this work, we demonstrated how such materials could be obtained from the parent material by using the aqueous two-phase extraction method (ATPE) at a large scale. We also developed a dedicated process on how to harvest the SWCNTs from the polymer matrices used to form the biphasic system. The technique is beneficial as it isolates SWCNTs with high purity while simultaneously maintaining their surface intact. To validate the utility of the metallic and semiconducting SWCNTs obtained this way, we transformed them into thin free-standing films and characterized their thermoelectric properties.


Carbon Trends ◽  
2021 ◽  
Vol 3 ◽  
pp. 100026
Author(s):  
Marcelo Eising ◽  
Colin O'Callaghan ◽  
Carlos Eduardo Cava ◽  
Ariane Schmidt ◽  
Aldo José Gorgatti Zarbin ◽  
...  

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