Oxygen-Induced Doping of Spiro-MeOTAD in Solid-State Dye-Sensitized Solar Cells and Its Impact on Device Performance

Nano Letters ◽  
2012 ◽  
Vol 12 (9) ◽  
pp. 4925-4931 ◽  
Author(s):  
Ute B. Cappel ◽  
Torben Daeneke ◽  
Udo Bach
2004 ◽  
Vol 836 ◽  
Author(s):  
Lukas Schmidt-Mende ◽  
Shaik M. Zakeeruddin ◽  
Michael Grätzel

ABSTRACTWe report a solid-state dye-sensitized solar cell with a record efficiency of 4% under simulated sunlight (AM1.5global, 100mW/cm2). This was made possible by using a new amphiphilic dye with hydrophobic spacers in combination with spiro-OMeTAD. We attribute the significant improvement in the device performance to the self-assembly of the dye to form a compact layer on the TiO2 surface and to the hydrophobic chains working as blocking layer between spiro-OMeTAD and TiO2 to reduce the back electron transfer. In addition, we studied the influence of nanoporous TiO2 film thickness on the performance of the device. These results demonstrate the high potential for solid state dye sensitized solar cells to compete with amorphous silicon cells as low cost alternative.


2009 ◽  
Vol 19 (15) ◽  
pp. 2431-2436 ◽  
Author(s):  
I-Kang Ding ◽  
Nicolas Tétreault ◽  
Jérémie Brillet ◽  
Brian E. Hardin ◽  
Eva H. Smith ◽  
...  

2006 ◽  
Vol 90 (5) ◽  
pp. 549-573 ◽  
Author(s):  
Bin Li ◽  
Liduo Wang ◽  
Bonan Kang ◽  
Peng Wang ◽  
Yong Qiu

Molecules ◽  
2020 ◽  
Vol 25 (1) ◽  
pp. 198 ◽  
Author(s):  
Michèle Chevrier ◽  
Alberto Fattori ◽  
Laurent Lasser ◽  
Clément Kotras ◽  
Clémence Rose ◽  
...  

Chlorophyll a derivatives were integrated in “all solid-state” dye sensitized solar cells (DSSCs) with a mesoporous TiO2 electrode and 2′,2′,7,7′-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene as the hole-transport material. Despite modest power conversion efficiencies (PCEs) between 0.26% and 0.55% achieved for these chlorin dyes, a systematic investigation was carried out in order to elucidate their main limitations. To provide a comprehensive understanding of the parameters (structure, nature of the anchoring group, adsorption …) and their relationship with the PCEs, density functional theory (DFT) calculations, optical and photovoltaic studies and electron paramagnetic resonance analysis exploiting the 4-carboxy-TEMPO spin probe were combined. The recombination kinetics, the frontier molecular orbitals of these DSSCs and the adsorption efficiency onto the TiO2 surface were found to be the key parameters that govern their photovoltaic response.


2019 ◽  
Vol 7 (7) ◽  
pp. 7403-7411 ◽  
Author(s):  
Shanmuganathan Venkatesan ◽  
I-Ping Liu ◽  
Chiao-Wei Li ◽  
Chih-Mei Tseng-Shan ◽  
Yuh-Lang Lee

2011 ◽  
Vol 21 (24) ◽  
pp. 4633-4639 ◽  
Author(s):  
Jeonghun Kim ◽  
Jong Kwan Koh ◽  
Byeonggwan Kim ◽  
Sung Hoon Ahn ◽  
Hyungju Ahn ◽  
...  

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