Comments on “NanoTeflons:  Structure and EELS Characterization of Fluorinated Carbon Nanotubes and Nanofibers”

A novel phosphorus-silicon containing flame-retardant DOPO-V-PA was used to wrap carbon nanotubes (CNTs). The results of FTIR, XPS, TEM and TGA measurements exhibited that DOPO-V-PA has been successfully grafted onto the surfaces of CNTs, and the CNTs-DOPO-V-PA was obtained. The CNTs-DOPO-V-PA was subsequently incorporated into epoxy resin (EP) for improving the flame retardancy and dispersion. Compared with pure EP, the addition of 2 wt% CNTs-DOPO-V-PA into the EP matrix could achieve better flame retardancy of EP nanocomposites, such as a 30.5% reduction in peak heat release rate (PHRR) and 8.1% reduction in total heat release (THR). Furthermore, DMTA results clearly indicated that the dispersion for CNTs-DOPO-V-PA in EP matrix was better than pristine CNTs.

Download Full-text

Fluorinated graphene nanoribbons from unzipped single-walled carbon nanotubes for ultrahigh energy density lithium-fluorinated carbon batteries

Science China Materials ◽

10.1007/s40843-020-1551-x ◽

2021 ◽

Author(s):

Cong Peng ◽

Lingchen Kong ◽

Yu Li ◽

Haoyu Fu ◽

Lidong Sun ◽

...

Keyword(s):

Carbon Nanotubes ◽

Energy Density ◽

Graphene Nanoribbons ◽

Single Walled Carbon Nanotubes ◽

Ultrahigh Energy ◽

Single Walled Carbon ◽

Fluorinated Graphene ◽

Fluorinated Carbon ◽

Walled Carbon Nanotubes

Download Full-text

Optical Absorption Spectroscopy of DNA-Wrapped HiPco Carbon Nanotubes

Materials Science Forum ◽

10.4028/www.scientific.net/msf.943.95 ◽

2019 ◽

Vol 943 ◽

pp. 95-99

Author(s):

Li Jun Wang ◽

Kazuo Umemura

Keyword(s):

Carbon Nanotubes ◽

Aqueous Solution ◽

Optical Absorption ◽

Absorption Spectroscopy ◽

Near Infrared ◽

Nir Spectroscopy ◽

Optical Characterization ◽

Optical Absorption Spectroscopy ◽

Double Stranded Dna

Optical absorption spectroscopy provides evidence for individually dispersed carbon nanotubes. A common method to disperse SWCNTs into aqueous solution is to sonicate the mixture in the presence of a double-stranded DNA (dsDNA). In this paper, optical characterization of dsDNA-wrapped HiPco carbon nanotubes (dsDNA-SWCNT) was carried out using near infrared (NIR) spectroscopy and photoluminescence (PL) experiments. The findings suggest that SWCNT dispersion is very good in the environment of DNA existing. Additionally, its dispersion depends on dsDNA concentration.

Download Full-text

Synthesis and Characterization of Poly(2,5-benzimidazole) (ABPBI) Grafted Carbon Nanotubes

MRS Proceedings ◽

10.1557/proc-1240-ww09-02 ◽

2009 ◽

Vol 1240 ◽

Cited By ~ 1

Author(s):

Ji-Ye Kang ◽

Su-Mi Eo ◽

Loon-Seng Tan ◽

Jong-Beom Baek

Keyword(s):

Carbon Nanotubes ◽

Carbon Nanotube ◽

Interfacial Adhesion ◽

Synthesis And Characterization ◽

Acylation Reaction ◽

Single Walled Carbon Nanotube ◽

Mechanical And Electrical Properties ◽

Multi Walled Carbon Nanotube

AbstractSingle-walled carbon nanotube (SWCNT) and multi-walled carbon nanotube (MWCNT) were functionalized with 3,4-diaminobenzoic acid via “direct” Friedel-Crafts acylation reaction in PPA/P2O5 to afford ortho-diamino-functionalized SWCNT (DIF-SWCNT) and MWCNT (DIF-MWCNT). The resultant DIF-SWCNT and DIF-MWCNT showed improved solubility and dispersibility. To improve interfacial adhesion between CNT and polymer matrix, the grafting of ABPBI onto the surface of DIF-SWCNT (10 wt%) or DIF-MWCNT (10 wt%) was conducted by simple in-situ polymerization of AB monomer, 3,4-diaminobenzoic acid dihydrochloride, in PPA. The resultant ABPBI-g-MWCNT and ABPBI-g-SWCNT showed improved the mechanical and electrical properties.

Download Full-text