Conjugated Porous Polymers For TNT Vapor Detection

2013 ◽  
Vol 2 (5) ◽  
pp. 423-426 ◽  
Author(s):  
Jennifer L. Novotney ◽  
William R. Dichtel
2011 ◽  
Vol 26 (10) ◽  
pp. 1111-1115 ◽  
Author(s):  
Tian-Tian YANG ◽  
Peng-Cheng XU ◽  
Guo-Min ZUO ◽  
Xin-Xin LI

2021 ◽  
Vol 175 ◽  
pp. 396-405
Author(s):  
Luyan Sun ◽  
Kungang Chai ◽  
Liqin Zhou ◽  
Dankui Liao ◽  
Hongbing Ji

ACS Sensors ◽  
2021 ◽  
Author(s):  
Maxwell Wei-Hao Li ◽  
Abhishek Ghosh ◽  
Anandram Venkatasubramanian ◽  
Ruchi Sharma ◽  
Xiaolu Huang ◽  
...  

Small Science ◽  
2021 ◽  
Vol 1 (6) ◽  
pp. 2170015
Author(s):  
Yeongran Hong ◽  
Vepa Rozyyev ◽  
Cafer T. Yavuz

2021 ◽  
Author(s):  
Narendran Rajendran ◽  
Ali A. Husain ◽  
Saad Makhseed

Three new carbazole containing cross-linked polymers namely AH-Poly, TM-PDA-Poly and TMB-PDA-Poly were designed and successfully synthesized by an oxidative polymerization protocol. The prepared AH-Poly showed a specific BET surface area...


Chemosensors ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 1
Author(s):  
Miao Zhang ◽  
Jiangfan Shi ◽  
Chenglong Liao ◽  
Qingyun Tian ◽  
Chuanyi Wang ◽  
...  

Perylene imide (PI) molecules and materials have been extensively studied for optical chemical sensors, particularly those based on fluorescence and colorimetric mode, taking advantage of the unique features of PIs such as structure tunability, good thermal, optical and chemical stability, strong electron affinity, strong visible light absorption and high fluorescence quantum yield. PI-based optical chemosensors have now found broad applications in gas phase detection of chemicals, including explosives, biomarkers of some food and diseases (such as organic amines (alkylamines and aromatic amines)), benzene homologs, organic peroxides, phenols and nitroaromatics, etc. In this review, the recent research on PI-based fluorometric and colorimetric sensors, as well as array technology incorporating multiple sensors, is reviewed along with the discussion of potential applications in environment, health and public safety areas. Specifically, we discuss the molecular design and aggregate architecture of PIs in correlation with the corresponding sensor performances (including sensitivity, selectivity, response time, recovery time, reversibility, etc.). We also provide a perspective summary highlighting the great potential for future development of PIs optical chemosensors, especially in the sensor array format that will largely enhance the detection specificity in complexed environments.


2021 ◽  
pp. 2105384
Author(s):  
Laura Collado ◽  
Teresa Naranjo ◽  
Miguel Gomez‐Mendoza ◽  
Carmen G. López‐Calixto ◽  
Freddy E. Oropeza ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2047
Author(s):  
Naofumi Naga ◽  
Mitsusuke Sato ◽  
Kensuke Mori ◽  
Hassan Nageh ◽  
Tamaki Nakano

Addition reactions of multi-functional amine, polyethylene imine (PEI) or diethylenetriamine (DETA), and poly(ethylene glycol) diglycidyl ether (PEGDE) or poly(ethylene glycol) diacrylate (PEGDA), have been investigated to obtain network polymers in H2O, dimethyl sulfoxide (DMSO), and ethanol (EtOH). Ring opening addition reaction of the multi-functional amine and PEGDE in H2O at room temperature or in DMSO at 90 °C using triphenylphosphine as a catalyst yielded gels. Aza-Michael addition reaction of the multi-functional amine and PEGDA in DMSO or EtOH at room temperature also yielded corresponding gels. Compression test of the gels obtained with PEI showed higher Young’s modulus than those with DETA. The reactions of the multi-functional amine and low molecular weight PEGDA in EtOH under the specific conditions yielded porous polymers induced by phase separation during the network formation. The morphology of the porous polymers could be controlled by the reaction conditions, especially monomer concentration and feed ratio of the multi-functional amine to PEGDA of the reaction system. The porous structure was formed by connected spheres or a co-continuous monolithic structure. The porous polymers were unbreakable by compression, and their Young’s modulus increased with the increase in the monomer concentration of the reaction systems. The porous polymers absorbed various solvents derived from high affinity between the polyethylene glycol units in the network structure and the solvents.


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