Dibromomaleimide End Functional Polymers by RAFT Polymerization Without the Need of Protecting Groups

2011 ◽  
Vol 1 (1) ◽  
pp. 222-226 ◽  
Author(s):  
Mathew P. Robin ◽  
Mathew W. Jones ◽  
David M. Haddleton ◽  
Rachel K. O’Reilly
Keyword(s):  
Raft Polymerization ◽  
Functional Polymers ◽  
Protecting Groups

Functional polymers for optoelectronic applications by RAFT polymerization

2011 ◽  
Vol 2 (3) ◽  
pp. 492-519 ◽  
Author(s):  
Graeme Moad ◽  
Ming Chen ◽  
Matthias Häussler ◽  
Almar Postma ◽  
Ezio Rizzardo ◽  
...  
Keyword(s):  
Raft Polymerization ◽  
Functional Polymers ◽  
Optoelectronic Applications

Photolabile protecting groups: a strategy for making primary amine polymers by RAFT

2018 ◽  
Vol 9 (13) ◽  
pp. 1557-1561 ◽  
Author(s):  
Nethmi De Alwis Watuthanthrige ◽  
Pierce N. Kurek ◽  
Dominik Konkolewicz
Keyword(s):  
Primary Amine ◽  
Raft Polymerization ◽  
Protecting Groups ◽  
Photolabile Protecting Groups

Photolabile amine protecting groups are combined with RAFT polymerization to create well-defined amine containing polymers, which is typically a challenge for RAFT polymerization.

One pot synthesis of higher order quasi-block copolymer librariesviasequential RAFT polymerization in an automated synthesizer

2014 ◽  
Vol 5 (18) ◽  
pp. 5236-5246 ◽  
Author(s):  
Joris J. Haven ◽  
Carlos Guerrero-Sanchez ◽  
Daniel J. Keddie ◽  
Graeme Moad ◽  
San H. Thang ◽  
...  
Keyword(s):  
Block Copolymer ◽  
High Throughput ◽  
Raft Polymerization ◽  
Functional Polymers ◽  
Higher Order ◽  
One Pot ◽  
One Pot Synthesis ◽  
The One

The utility of automated high-throughput methods for the one pot synthesis of functional polymers of increased complexity is reported.

A Novel One-Pot Procedure for the Fast and Efficient Conversion of RAFT Polymers into Hydroxy-Functional Polymers

2009 ◽  
Vol 62 (8) ◽  
pp. 806 ◽  
Author(s):  
Till Gruendling ◽  
Mathias Dietrich ◽  
Christopher Barner-Kowollik
Keyword(s):  
Elevated Temperatures ◽  
Raft Polymerization ◽  
Functional Polymers ◽  
Size Exclusion ◽  
One Pot ◽  
Reversible Addition ◽  
Exclusion Chromatography ◽  
Azo Initiator ◽  
Raft Polymers ◽  
End Group

We report on the successful quantitative transformation of methacrylate and acrylate-type polymers prepared by reversible addition–fragmentation chain transfer (RAFT) polymerization carrying a dithioester-end-group into hydroxy-functional polymers. The simple reaction procedure involves stirring a solution of the dithioester-capped polymer and an azo-initiator in tetrahydrofuran at elevated temperatures (T = 60°C) in the presence of air. This reaction quantitatively yields hydroperoxide functionalities that can be efficiently reduced to hydroxy groups in a one-pot procedure using triphenylphosphine. Size exclusion chromatography–electrospray mass spectrometry was employed to monitor the progress of the reaction. The new backbone-linked hydroxy group provides a versatile anchor for chemical end-group conversions and conjugation reactions with prepared RAFT polymers, which alleviates problems with the rather limited ability of the dithioester-end-group to undergo non-radical transformations.

scholarly journals Poly(thioacrylate)s: expanding the monomer toolbox of functional polymers

2016 ◽  
Vol 7 (45) ◽  
pp. 7011-7018 ◽  
Author(s):  
Suzan Aksakal ◽  
C. Remzi Becer
Keyword(s):  
Raft Polymerization ◽  
Functional Polymers ◽  
First Time

A facile method for synthesizing thioacrylate monomers and their RAFT polymerization have been demonstrated for the first time.

scholarly journals Precise Synthesis of Functional Polymers by RAFT Polymerization

2007 ◽  
Vol 64 (10) ◽  
pp. 655-664
Author(s):  
Hideharu MORI ◽  
Takeshi ENDO
Keyword(s):  
Raft Polymerization ◽  
Functional Polymers
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