scholarly journals Liquid–Liquid Miscibility Gaps in Drug–Water Binary Systems: Crystal Structure and Thermodynamic Properties of Prilocaine and the Temperature–Composition Phase Diagram of the Prilocaine–Water System

2013 ◽  
Vol 10 (4) ◽  
pp. 1332-1339 ◽  
Author(s):  
Ivo B. Rietveld ◽  
Marc-Antoine Perrin ◽  
Siro Toscani ◽  
Maria Barrio ◽  
Beatrice Nicolai ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Phase Diagram ◽  
Thermodynamic Properties ◽  
Binary Systems ◽  
Water System ◽  
Miscibility Gaps

Calculation of phase diagrams and thermodynamic properties of 14 additive and reciprocal ternary systems containing Li2CO3, Na2CO3, K2CO3, Li2SO4, Na2SO4, K2SO4, LiOH, NaOH, and KOH

1984 ◽  
Vol 62 (3) ◽  
pp. 457-474 ◽  
Author(s):  
A. D. Pelton ◽  
C. W. Bale ◽  
P. L. Lin
Keyword(s):  
Phase Diagram ◽  
Thermodynamic Properties ◽  
Molten Salt ◽  
Phase Diagrams ◽  
Binary Systems ◽  
Ternary Phase ◽  
Ternary Phase Diagram ◽  
Ternary Systems ◽  
Maximum Error ◽  
Critical Assessment

Phase diagrams and thermodynamic properties of five additive molten salt ternary systems and nine reciprocal molten salt ternary systems containing the ions Li+, Na+, [Formula: see text], OH− are calculated from the thermodynamic properties of their binary subsystems which were obtained previously by a critical assessment of the thermodynamic data and the phase diagrams in these binary systems. Thermodynamic properties of ternary liquid phases are estimated from the binary properties by means of the Conformal Ionic Solution Theory. The ternary phase diagrams are then calculated from these thermodynamic properties by means of computer programs designed for the purpose. It is found that a ternary phase diagram can generally be calculated in this way with a maximum error about twice that of the maximum error in the binary phase diagrams upon which the calculations are based. If, in addition, some reliable ternary phase diagram measurements are available, these can be used to obtain small ternary correction terms. In this way, ternary phase diagram measurements can be smoothed and the isotherms drawn in a thermodynamically correct way. The thermodynamic approach permits experimental data to be critically assessed in the light of thermodynamic principles and accepted solution models. A critical assessment of error limits on all the calculated ternary diagrams is made, and suggestions as to which composition regions merit further experimental study are given.

A Thermodynamic Approach to the Calculation of the C-Cr-Nb-Ni-W Phase Diagram

1982 ◽  
Vol 19 ◽  
Author(s):  
P.Y. Chevalier ◽  
J.N. Barbier ◽  
I. Ansara
Keyword(s):  
Phase Diagram ◽  
Thermodynamic Properties ◽  
Binary Systems ◽  
Thermodynamic Approach ◽  
Phase Boundaries ◽  
Quaternary Systems ◽  
Methods Of Calculation

ABSTRACTThe phase boundaries of the C-Cr-Nb-Ni-W system are calculated from the available thermodynamic properties of the limiting binary systems. The methods of calculation and the models used in the description of the ternary and quaternary systems are presented as well as the influence of tungsten on the solubility of the M23C6 phase in the nickel rich alloys.

Thermodynamic Calculation of the Rare Earth Permanent Magnets: Fe-RE (RE=Ho, Er, Tm, Sm) Binary Systems

2017 ◽  
Vol 898 ◽  
pp. 1042-1047
Author(s):  
M.H. Rong ◽  
X.L. Chen ◽  
Jiang Wang ◽  
S.D. Lin ◽  
G.H. Rao ◽  
...  
Keyword(s):  
Experimental Data ◽  
Phase Diagram ◽  
Thermodynamic Properties ◽  
Thermodynamic Calculation ◽  
Binary Systems ◽  
Permanent Magnets ◽  
Ternary Systems ◽  
Calculated Phase Diagram ◽  
Experimental Information ◽  
Microstructure And Magnetic Properties

The experimental data of phase equilibria and thermodynamic properties of the Fe-RE (RE=Ho, Er, Tm, Sm) binary systems were reviewed. The previous thermodynamic calculation of the Fe-RE (RE=Ho, Er, Tm, Sm) binary systems were discussed based on the comparison of the calculated phase diagram and thermodynamic properties with the experimental data. The compared results show that more experimental information of phase diagram and thermodynamic properties in the Fe-RE (RE=Ho, Er, Tm, Sm) binary systems should be determined and then thermodynamic re-calculation of these binary systems would be performed to develop compatible and available thermodynamic database of the RE-Fe-B ternary systems. It is indispensable to study the relations between alloy compositions, microstructure and magnetic properties of novel Nd-Fe-B-based permanent magnets.

Phase diagram measurements and thermodynamic analysis of the PbCl2–NaCl, PbCl2–KCl, and PbCl2–KCl–NaCl systems

1985 ◽  
Vol 63 (11) ◽  
pp. 3276-3282 ◽  
Author(s):  
Armand Gabriel ◽  
Arthur D. Pelton
Keyword(s):  
Phase Diagram ◽  
Thermodynamic Properties ◽  
Binary Data ◽  
Binary Systems ◽  
Ternary Phase Diagram ◽  
Correction Term ◽  
Cooling Curve ◽  
Mathematical Expressions ◽  
Solution Equation ◽  
Thermodynamic Phase

The phase diagrams of the PbCl2–NaCl and PbCl2–KCl systems have been measured by the cooling curve technique. In addition, a number of measurements at compositions in the ternary system PbCl2–KCl–NaCl have been made. The binary data have been analysed along with other available thermodynamic data for the binary systems in order to obtain mathematical expressions for the binary thermodynamic properties. Various estimation procedures were then used to calculate the Gibbs energy of the ternary liquid from the binary expressions, and the ternary phase diagram calculated therefrom was compared to the experimental ternary points. In the case of the Conformal Ionic Solution equation, agreement was within 3 °C at all measured points. In the case of two "geometric" estimation techniques, the Kohler and Toop equations, agreement was within 10 °C but could be brought to within 3 °C by the addition of only one small adjustable ternary correction term. The technique of coupled thermodynamic/phase diagram analysis permits a large reduction in the amount of experimental work necessary to measure the ternary diagram. In addition, the ternary thermodynamic expressions developed can be used to calculate all thermodynamic properties of the ternary liquid.

Thermodynamic Properties and Phase Equilibria in the Ternary Cu-Pb-Fe System

2013 ◽  
Vol 58 (2) ◽  
pp. 541-548 ◽  
Author(s):  
B. Onderka ◽  
D. Jendrzejczyk-Handzlik ◽  
K. Fitzner
Keyword(s):  
Experimental Data ◽  
Phase Diagram ◽  
Thermodynamic Properties ◽  
Phase Equilibria ◽  
Thermodynamic Functions ◽  
Binary Systems ◽  
Liquid Solution ◽  
Calculated Diagram ◽  
Calculated Equilibrium ◽  
Good Agreement

Using experimental data available in the literature, two binary systems, namely Cu-Pb and Fe-Pb were recalculated. Next, accepting Cu-Fe phase diagram assessment as given by Ansara and Jansson, the ternary Cu-Fe-Pb system was analyzed. Calculated equilibrium lines and thermodynamic functions are compared with existing experimental data. Good agreement was found between the calculated diagram and the experimental results. Having the system optimized, functional dependences of the logarithms of the activity coefficients on temperature and concentrations for Cu, Fe and Pb in the liquid solution are given.

An Updated Phase Diagram of the SnTe-Sb2Te3 System and the Crystal Structure of the New Compound SnSb4Te7

2021 ◽  
Author(s):  
Aynur E. Seidzade ◽  
Elnur N. Orujlu ◽  
Thomas Doert ◽  
Imamaddin R. Amiraslanov ◽  
Ziya S. Aliev ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Phase Diagram

Phase diagram of the Sb–Te–I system and thermodynamic properties of SbTeI

2012 ◽  
Vol 103 (3) ◽  
pp. 290-295 ◽  
Author(s):  
Ziya S. Aliev ◽  
Mahammad B. Babanly ◽  
Andrei V. Shevelkov ◽  
Dunya M. Babanly ◽  
Jean-Claude Tedenac
Keyword(s):  
Phase Diagram ◽  
Thermodynamic Properties
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