Topographical Structure of Solid Films of Poly[5,7-dodecadiyne-1,12-diolbis(4-butoxycarbonyl methylurethane)] Self-Assembled from Its Lyotropic Liquid Crystal Phase†

2000 ◽  
Vol 33 (6) ◽  
pp. 2055-2059 ◽  
Author(s):  
Kee Chua Toh ◽  
Wei Wang
Keyword(s):  
Liquid Crystal ◽  
Lyotropic Liquid Crystal ◽  
Crystal Phase ◽  
Liquid Crystal Phase ◽  
Solid Films ◽  
Self Assembled

Self-assembled hydrophobic surface generated from a helical nanofilament (B4) liquid crystal phase

Soft Matter ◽  
2013 ◽  
Vol 9 (10) ◽  
pp. 2793 ◽  
Author(s):  
Hanim Kim ◽  
Youngwoo Yi ◽  
Dong Chen ◽  
Eva Korblova ◽  
David M. Walba ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Hydrophobic Surface ◽  
Crystal Phase ◽  
Liquid Crystal Phase ◽  
Self Assembled

The pathway and kinetics of hierarchical assembly of ionic oligomers into a lyotropic columnar phase

Soft Matter ◽  
2019 ◽  
Vol 15 (22) ◽  
pp. 4460-4466
Author(s):  
Weiheng Huang ◽  
Shenghui Wei ◽  
Daan Frenkel ◽  
Ningdong Huang
Keyword(s):  
Liquid Crystal ◽  
Supramolecular Assembly ◽  
Lyotropic Liquid Crystal ◽  
Crystal Phase ◽  
Liquid Crystal Phase ◽  
Hierarchical Assembly ◽  
Columnar Phase ◽  
Kinetics Of

In situ investigations on the formation of a lyotropic liquid crystal phase through supramolecular assembly in solution suggest a multi-step pathway.

Lyotropic liquid crystal phase behavior of polymeric siloxane surfactants

Langmuir ◽  
1993 ◽  
Vol 9 (11) ◽  
pp. 2789-2798 ◽  
Author(s):  
Randal M. Hill ◽  
Mengtao He ◽  
Zuchen Lin ◽  
H. Ted Davis ◽  
L. E. Scriven
Keyword(s):  
Liquid Crystal ◽  
Phase Behavior ◽  
Lyotropic Liquid Crystal ◽  
Crystal Phase ◽  
Liquid Crystal Phase

Rigid-Rod And Segmented Rigid-Rod Polyimides: GEL/SOL And Liquid Crystalline Transitions, Fibers And Films

1991 ◽  
Vol 227 ◽  
Author(s):  
Stephen Z. D. Cheng ◽  
Fred E. Arnold ◽  
Mark Eashoo ◽  
Song-Koo Lee ◽  
Steve L. C. Hsu ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
High Performance ◽  
Liquid Crystalline ◽  
Elevated Temperatures ◽  
Dielectric Constants ◽  
Lyotropic Liquid Crystal ◽  
Crystal Phase ◽  
Liquid Crystal Phase ◽  
Initial Modulus ◽  
Rigid Rod

ABSTRACTOrgano-soluble rigid-rod and segmented rigid-rod polyimides and their copolyimides exhibit isotropic solutions in hot m-cresol, but form gels upon cooling. A lyotropic liquid crystal phase is observed below the gel/sol transition. Mechanical gel formation is caused by liquid-liquid phase separation, while the liquid crystal phase may be formed through a nucleation process after gelation. High performance fibers can be spun from the hot isotropic solutions using a dry-jet wet spinning method. After the fibers are drawn at high temperatures, they display tensile strength higher than 3.2 GPa and an initial modulus higher than 130 GPa. In particular, the fibers retain relatively high mechanical properties at elevated temperatures. Solution casted films exhibit very low thermal expansion coefficients and dielectric constants. Their structure, morphology and property relationships will also be discussed.

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