Polymers at Interfaces:  Using Atom Transfer Radical Polymerization in the Controlled Growth of Homopolymers and Block Copolymers from Silicon Surfaces in the Absence of Untethered Sacrificial Initiator

1999 ◽  
Vol 32 (26) ◽  
pp. 8716-8724 ◽  
Author(s):  
Krzysztof Matyjaszewski ◽  
Peter J. Miller ◽  
Nisha Shukla ◽  
Boonchuan Immaraporn ◽  
Andrew Gelman ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Silicon Surfaces ◽  
Controlled Growth ◽  
Atom Transfer

scholarly journals Synthesis of Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) Block Copolymer by Redox Polymerization and Atom Transfer Radical Polymerization

2018 ◽  
Vol 18 (3) ◽  
pp. 537 ◽  
Author(s):  
Melahat Göktaş ◽  
Guodong Deng
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Gel Permeation Chromatography ◽  
High Yield ◽  
Resonance Spectroscopy ◽  
Atom Transfer ◽  
Poly Methyl Methacrylate ◽  
Redox Polymerization

Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) [PMMA-b-PNIPAM] block copolymers were obtained by a combination of redox polymerization and atom transfer radical polymerization (ATRP) methods in two steps. For this purpose, PMMA macroinitator (ATRP-macroinitiator) was synthesized by redox polymerization of methyl methacrylate and 3-bromo-1-propanol using Ce(NH4)2(NO3)6 as a catalyst. The synthesis of PMMA-b-PNIPAM block copolymers was carried out by means of ATRP of ATRP-macroinitiator and NIPAM at 60 °C. The block copolymers were obtained in high yield and high molecular weight. The characterization of products was accomplished by using multi instruments and methods such as nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, gel permeation chromatography, and thermogravimetric analysis.

Synthesis of Amphiphilic Block Copolymers by Atom Transfer Radical Polymerization (ATRP)

1998 ◽  
Vol 31 (18) ◽  
pp. 6046-6052 ◽  
Author(s):  
Andreas Mühlebach ◽  
Scott G. Gaynor ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Amphiphilic Block Copolymers ◽  
Atom Transfer

Facile synthesis of well-controlled poly(glycidyl methacrylate) and its block copolymers via SARA ATRP at room temperature

2015 ◽  
Vol 6 (10) ◽  
pp. 1875-1882 ◽  
Author(s):  
Francisco Catalão ◽  
Joana R. Góis ◽  
A. S. M. Trino ◽  
Arménio C. Serra ◽  
Jorge F. J. Coelho
Keyword(s):  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Catalytic System ◽  
Glycidyl Methacrylate ◽  
Room Temperature ◽  
Atom Transfer ◽  
Facile Synthesis

The detailed synthesis of poly(glycidyl methacrylate) (PGMA) by atom transfer radical polymerization (ATRP) using a catalytic system of Fe(0)/Cu(ii)Br2 at room temperature is reported.

Sign in / Sign up

Export Citation Format

Share Document