Conformational Properties of Poly(vinylidene fluoride). A Quantum Chemistry Study of Model Compounds

1999 ◽  
Vol 32 (25) ◽  
pp. 8376-8382 ◽  
Author(s):  
Oleksiy G. Byutner ◽  
Grant D. Smith
Keyword(s):  
Quantum Chemistry ◽  
Vinylidene Fluoride ◽  
Model Compounds ◽  
Conformational Properties ◽  
Poly Vinylidene Fluoride

Conformational properties of poly(vinylidene bromide) and poly(vinylidene fluoride)

1990 ◽  
Vol 23 (5) ◽  
pp. 1309-1312 ◽  
Author(s):  
Luis Carballeira ◽  
A. J. Pereiras ◽  
M. A. Rios
Keyword(s):  
Vinylidene Fluoride ◽  
Conformational Properties ◽  
Poly Vinylidene Fluoride

Quantum Chemistry Based Force Field for Simulations of Poly(vinylidene fluoride)

2000 ◽  
Vol 33 (11) ◽  
pp. 4264-4270 ◽  
Author(s):  
Oleksiy G. Byutner ◽  
Grant D. Smith
Keyword(s):  
Quantum Chemistry ◽  
Force Field ◽  
Vinylidene Fluoride ◽  
Poly Vinylidene Fluoride

Effect of Dipolar Side Groups on Conformational Properties of Heteroatom Polymers

2011 ◽  
Vol 308-310 ◽  
pp. 696-700
Author(s):  
Hai Zhu Ma ◽  
Xin Du ◽  
Ting Ting Sun
Keyword(s):  
Dipole Moment ◽  
Electric Dipole ◽  
Vinylidene Fluoride ◽  
Radius Of Gyration ◽  
Inorganic Polymers ◽  
Mean Square ◽  
Characteristic Quantity ◽  
Unperturbed Dimensions ◽  
Conformational Properties ◽  
Poly Vinylidene Fluoride

The unperturbed dimensions of symmetric polymers are investigated by an improved conformational statistic method considering effect of side groups. Following the deduced formulas, the characteristic ratios of mean-square radius of gyration for poly(dimethylsilmethylene) (PDMSM), poly(vinylidene fluoride)(PVDF), polyphosphate(PP), polyoxymethylene(POM) and poyisobutylene (PIB) are calculated 0.69, 0.84, 1.23, 0.85 and 1.18, respectively. The ratios of mean-square dipole moment are 0.35, 0.48, 0.59 and 0.79 for PP, PDMSM, POM and PVDF long chains, respectively. From comparing the ratios of five polymers, it is found that the consideration of side groups for short chains is exceedingly important in calculation of characteristic quantity, especially for the inorganic polymers with heteroatom. PVDF are excellent in flexibility and electric dipole properties. The temperature characters of PIB are concerned closely with its conformational energy.

Piezoelectric β-polymorph formation of new textiles by surface modification with coating process based on interfacial interaction on the conformational variation of poly (vinylidene fluoride) (PVDF) chains

2020 ◽  
Vol 91 (3) ◽  
pp. 31301
Author(s):  
Nabil Chakhchaoui ◽  
Rida Farhan ◽  
Meriem Boutaldat ◽  
Marwane Rouway ◽  
Adil Eddiai ◽  
...  
Keyword(s):  
High Efficiency ◽  
Vinylidene Fluoride ◽  
Research Work ◽  
Research Area ◽  
Interfacial Interaction ◽  
Tetraethyl Orthosilicate ◽  
Poly Vinylidene Fluoride ◽  
Carbon Nanofillers ◽  
The Impact ◽  
Advanced Applications

Novel textiles have received a lot of attention from researchers in the last decade due to some of their unique features. The introduction of intelligent materials into textile structures offers an opportunity to develop multifunctional textiles, such as sensing, reacting, conducting electricity and performing energy conversion operations. In this research work nanocomposite-based highly piezoelectric and electroactive β-phase new textile has been developed using the pad-dry-cure method. The deposition of poly (vinylidene fluoride) (PVDF) − carbon nanofillers (CNF) − tetraethyl orthosilicate (TEOS), Si(OCH2CH3)4 was acquired on a treated textile substrate using coating technique followed by evaporation to transform the passive (non-functional) textile into a dynamic textile with an enhanced piezoelectric β-phase. The aim of the study is the investigation of the impact the coating of textile via piezoelectric nanocomposites based PVDF-CNF (by optimizing piezoelectric crystalline phase). The chemical composition of CT/PVDF-CNC-TEOS textile was detected by qualitative elemental analysis (SEM/EDX). The added of 0.5% of CNF during the process provides material textiles with a piezoelectric β-phase of up to 50% has been measured by FTIR experiments. These results indicated that CNF has high efficiency in transforming the phase α introduced in the unloaded PVDF, to the β-phase in the case of nanocomposites. Consequently, this fabricated new textile exhibits glorious piezoelectric β-phase even with relatively low coating content of PVDF-CNF-TEOS. The study demonstrates that the pad-dry-cure method can potentially be used for the development of piezoelectric nanocomposite-coated wearable new textiles for sensors and energy harvesting applications. We believe that our study may inspire the research area for future advanced applications.

Effect of Carbon Nanotubes on the Shape Memory Performance of Poly(vinylidene fluoride)/Acrylic Blends

2013 ◽  
Vol 30 (2) ◽  
pp. 134
Author(s):  
Hui FU ◽  
Jishan QIU ◽  
Ning CHONG ◽  
Yaqing WANG ◽  
Yuanyuan TIAN ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Shape Memory ◽  
Vinylidene Fluoride ◽  
Memory Performance ◽  
Poly Vinylidene Fluoride
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