A Comprehensive Analysis of the Thermal Elimination Reaction in a Poly(p-phenylene vinylene) Precursor

1999 ◽  
Vol 32 (5) ◽  
pp. 1413-1423 ◽  
Author(s):  
Hiren V. Shah ◽  
Georgia A. Arbuckle
Keyword(s):  
Comprehensive Analysis ◽  
Phenylene Vinylene ◽  
Elimination Reaction ◽  
Thermal Elimination

A study of the thermal elimination reaction in a poly(p-phenylene vinylene) precursor

1996 ◽  
Vol 287 (2) ◽  
pp. 319-326 ◽  
Author(s):  
Hiren V. Shah ◽  
Andrew R. McGhie ◽  
Georgia A. Arbuckle
Keyword(s):  
Phenylene Vinylene ◽  
Elimination Reaction ◽  
Thermal Elimination

The Formation of Alkenes by the Thermal Elimination Reaction of N-Methyl-4-alkoxypyridinium Iodides. II. An Investigation of the Mechanism

1972 ◽  
Vol 50 (8) ◽  
pp. 1188-1191
Author(s):  
George H. Schmid ◽  
Aaron W. Wolkoff
Keyword(s):  
Elimination Reaction ◽  
Product Composition ◽  
Thermal Elimination ◽  
Leaving Group ◽  
Elimination Reactions ◽  
Leaving Groups

A comparison of the products from elimination reactions of a number of compounds containing various leaving groups with those containing the N-methyl oxypyridinium leaving group suggests that the elimination is not occurring by means of a simple E1 mechanism. Changing the anion of the salt from iodide to methyl-sulphate and tetrafluoroborate affects the product composition indicating that the anion is taking part in the reaction. The mechanism of this reaction appears to be on the E1-E2 borderline.

scholarly journals Isoxazole Formation by Thermal Elimination Reaction of 5-Substituted Isoxazolines

1972 ◽  
Vol 30 (10) ◽  
pp. 894-896 ◽  
Author(s):  
Yoshio IWAKURA ◽  
Keikichi UNO ◽  
Shinsaku SHIRAISHI ◽  
Masahiro YUYAMA ◽  
Yoshinori KIHARA
Keyword(s):  
Elimination Reaction ◽  
Thermal Elimination

Thermal Elimination Reaction of Aliphatic Amine Salts

1962 ◽  
Vol 27 (11) ◽  
pp. 4118-4120 ◽  
Author(s):  
C. Ainsworth ◽  
Nelson R. Easton
Keyword(s):  
Aliphatic Amine ◽  
Elimination Reaction ◽  
Thermal Elimination ◽  
Amine Salts

The Formation of Alkenes by the Thermal Elimination Reaction of N-Methyl-4-Alkoxypyridinium Iodides. I. Scope of the Reaction

1972 ◽  
Vol 50 (8) ◽  
pp. 1181-1187 ◽  
Author(s):  
George H. Schmid ◽  
Aaron W. Wolkoff
Keyword(s):  
Room Temperature ◽  
Elimination Reaction ◽  
Thermal Elimination ◽  
Alkyl Moiety ◽  
High Yields

Twenty-one 4-alkoxypyridines and their corresponding N-methyl-4-alkoxypyridinium iodides have been prepared and the latter pyrolyzed at temperatures ranging from room temperature to 185° to give the olefins derived from the alkyl moiety in high yields.

ChemInform Abstract: Synthesis of 3-Amino-4-methylidene-2-azetidinone via a Thermal Elimination Reaction.

ChemInform ◽  
2010 ◽  
Vol 23 (7) ◽  
pp. no-no
Author(s):  
S. H. KIM ◽  
G. NAM ◽  
E. S. JANG ◽  
D. Y. CHI ◽  
J.-H. KIM
Keyword(s):  
Elimination Reaction ◽  
Thermal Elimination
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