Functional Group Accessibility in Hydrogen-Bonded Polymer Blends. 3. Steric Shielding Effects

1998 ◽  
Vol 31 (23) ◽  
pp. 8423-8424 ◽  
Author(s):  
George J. Pehlert ◽  
Paul C. Painter ◽  
Michael M. Coleman
Keyword(s):  
Polymer Blends ◽  
Functional Group ◽  
Shielding Effects ◽  
Hydrogen Bonded

Functional Group Accessibility in Hydrogen-Bonded Polymer Blends. 2. Miscibility Map of 2,3-Dimethylbutadiene-stat-vinylphenol Blends with Ethylene-stat-vinyl acetate

1997 ◽  
Vol 30 (12) ◽  
pp. 3671-3677 ◽  
Author(s):  
George J. Pehlert ◽  
Paul C. Painter ◽  
Boris Veytsman ◽  
Michael M. Coleman
Keyword(s):  
Polymer Blends ◽  
Vinyl Acetate ◽  
Functional Group ◽  
Hydrogen Bonded

Prediction of the Phase Behaviour of Hydrogen-Bonded Polymer Blends

2006 ◽  
Vol 59 (8) ◽  
pp. 499 ◽  
Author(s):  
Michael M. Coleman ◽  
Paul C. Painter
Keyword(s):  
Polymer Blends ◽  
Functional Group ◽  
Equilibrium Constants ◽  
Phase Behaviour ◽  
Low Molecular Weight ◽  
Full Circle ◽  
Energy Of Mixing ◽  
The Subject ◽  
Free Energy Of Mixing ◽  
Hydrogen Bonded

In the early 1990s your authors believed that they had essentially solved the problem of predicting the phase behaviour of hydrogen-bonded polymer blends. A text devoted to this subject, Specific Interactions and the Miscibility of Polymer Blends, was published and we thought that it was now time to look around for something else to do. This was before a colleague, Boris Veytsman, pointed out that there was a flaw in our derivation of the free energy of mixing equation. It has taken us some 15 years to correct the theory and match the predictions of the phase behaviour of hydrogen-bonded blends that we presented in our 1991 book. So we have come full circle. The subject has become far more complicated, but at the same time far more interesting. Along the way we have discovered that the phase behaviour of hydrogen-bonded polymer blends can be successfully predicted using equilibrium constants determined from appropriate low molecular weight analogues, if chain connectivity effects such as intermolecular screening and functional group accessibility are included.

Functional Group Accessibility in Hydrogen Bonded Polymer Blends

1996 ◽  
Vol 29 (21) ◽  
pp. 6820-6831 ◽  
Author(s):  
Michael M. Coleman ◽  
George J. Pehlert ◽  
Paul C. Painter
Keyword(s):  
Polymer Blends ◽  
Functional Group ◽  
Hydrogen Bonded

Functional Group Accessibility in Hydrogen-Bonded Polymer Blends. 4. Cross-Linking Effects

2002 ◽  
Vol 35 (4) ◽  
pp. 1289-1298 ◽  
Author(s):  
Yin Hu ◽  
Valerie Gamble ◽  
Paul C. Painter ◽  
Michael M. Coleman
Keyword(s):  
Polymer Blends ◽  
Functional Group ◽  
Cross Linking ◽  
Hydrogen Bonded

Neutron reflectivity study of thin films of hydrogen-bonded polymer blends: influence of annealing on composition profile

1992 ◽  
Vol 25 (10) ◽  
pp. 2619-2623 ◽  
Author(s):  
Lei Jong ◽  
Eli M. Pearce ◽  
T. K. Kwei ◽  
W. A. Hamilton ◽  
G. S. Smith ◽  
...  
Keyword(s):  
Thin Films ◽  
Polymer Blends ◽  
Composition Profile ◽  
Neutron Reflectivity ◽  
Hydrogen Bonded

Correlation effects in hydrogen‐bonded polymer blends

1993 ◽  
Vol 99 (11) ◽  
pp. 9272-9278 ◽  
Author(s):  
Boris Veytsman ◽  
Paul Painter
Keyword(s):  
Polymer Blends ◽  
Correlation Effects ◽  
Hydrogen Bonded

Self-association versus interassociation in hydrogen bonded polymer blends: 1. Determination of equilibrium constants from miscible poly(2,6-dialkyl-4-vinyl phenol) blends

Polymer ◽  
1996 ◽  
Vol 37 (21) ◽  
pp. 4753-4761 ◽  
Author(s):  
Michael M. Coleman ◽  
George J. Pehlert ◽  
Xiaoming Yang ◽  
John B. Stallman ◽  
Paul C. Painter
Keyword(s):  
Polymer Blends ◽  
Equilibrium Constants ◽  
Self Association ◽  
Vinyl Phenol ◽  
Hydrogen Bonded

Light-Scattering Studies on Hydrogen-Bonded Polymer Blends

1994 ◽  
Vol 27 (24) ◽  
pp. 7139-7145 ◽  
Author(s):  
Dorab E. Bhagwagar ◽  
Paul C. Painter ◽  
Michael M. Coleman
Keyword(s):  
Light Scattering ◽  
Polymer Blends ◽  
Hydrogen Bonded
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