Solution Behavior and Self-Assembly of Complexes from Poly(α-methylstyrene)-block-poly(N-ethyl-4-vinylpyridinium) Cations and Aerosol OT Anions

1998 ◽  
Vol 31 (14) ◽  
pp. 4516-4519 ◽  
Author(s):  
Eugene A. Lysenko ◽  
Tatiana K. Bronich ◽  
Adi Eisenberg ◽  
Victor A. Kabanov ◽  
Alexander V. Kabanov
Keyword(s):  
Self Assembly ◽  
Solution Behavior ◽  
Aerosol Ot

Self-Assembly of Amphiphilic Poly(paraphenylene)s:  Thermotropic Phases, Solution Behavior, and Monolayer Films†

Langmuir ◽  
2003 ◽  
Vol 19 (16) ◽  
pp. 6537-6544 ◽  
Author(s):  
Tobias Fütterer ◽  
Thomas Hellweg ◽  
Gerhard H. Findenegg ◽  
Jörg Frahn ◽  
A. Dieter Schlüter ◽  
...  
Keyword(s):  
Self Assembly ◽  
Monolayer Films ◽  
Solution Behavior

Self-assembly of new surface active ionic liquids based on Aerosol-OT in aqueous media

2014 ◽  
Vol 428 ◽  
pp. 267-275 ◽  
Author(s):  
K. Srinivasa Rao ◽  
Praveen Singh Gehlot ◽  
Tushar J. Trivedi ◽  
Arvind Kumar
Keyword(s):  
Ionic Liquids ◽  
Self Assembly ◽  
Aqueous Media ◽  
Aerosol Ot ◽  
Surface Active

Purification, Characterization, and Self-Assembly of the Polysaccharides from Allium Schoenoprasum

2020 ◽  
Author(s):  
Fengrui Zhang ◽  
Jun Zheng ◽  
Zeyu Li ◽  
Zixuan Cai ◽  
Fengqiao Wang ◽  
...  
Keyword(s):  
Self Assembly ◽  
Tertiary Structure ◽  
Specific Binding ◽  
Gel Filtration ◽  
Spherical Particles ◽  
Molar Ratio ◽  
Hydrodynamic Behavior ◽  
Solution Behavior ◽  
Cylindrical Micelles ◽  
Allium Schoenoprasum

Abstract Background: Allium schoenoprasum is a world-wide common vegetable while only its leave is used in the food factory. Its stalk is largely discarded, for potential heavy metal accumulations, which eventually lead to an environmental contamination. To fully utilize this vegetable and minimize its metal content, the major polysaccharide content is purified and characterized with chemical and computational approaches.Results: The major polysaccharide component from the stalk of Allium schoenoprasum (AssP) was extracted and purified. The gel filtration chromatography purified AssP exhibited a molecular weight of around 1.6 kDa, which was verified by MALDI-ToF-MS. Monosaccharide analysis revealed its composition as rhamnose: arabinose: galactose: glucose: mannose: fructose with a molar ratio of 0.0264:2.46:3.71:3.35:1.00:9.93, respectively. Multiple NMR analysis revealed its backbone as α-Ara/Glu/Gal-(1→2)-linked and β-D-Fru-(4→5)-linked sugar residues. There was no tertiary structure of this polysaccharide, however, it self-assembled into a homogenous nanoparticle with a diameter of ~600 nm. The solution behavior of this AssP polysaccharide was simulated, and there was no specific binding site on one molecule for another. Association of this polysaccharide was concentration dependent. As the AssP concentration increased, the spherical particles increased their sizes and eventually merged into cylindrical micelles. The diversity of AssP hydrodynamic behavior endowed potential versatility in its applications.Conclusions: AssP was characterized as a polysaccharide with identified monosaccharide compositions and linkage between them. Although there is no tertiary structure in one AssP molecule, self-assembly of AssP molecules could form nanoparticles or micelles depending on its solution concentrations. The unique AssP solution behavior endows itself a potential biomaterial for nanoparticles preparations.

Effects of Block Length and Structure of Surfactant on Self-Assembly and Solution Behavior of Block Ionomer Complexes

Langmuir ◽  
2000 ◽  
Vol 16 (2) ◽  
pp. 481-489 ◽  
Author(s):  
Tatiana K. Bronich ◽  
Alexei M. Popov ◽  
Adi Eisenberg ◽  
Victor A. Kabanov ◽  
Alexander V. Kabanov
Keyword(s):  
Self Assembly ◽  
Block Length ◽  
Solution Behavior ◽  
Block Ionomer Complexes ◽  
Block Ionomer

Block Ionomer Complexes with Polystyrene Core-Forming Block in Selective Solvents of Various Polarities. 2. Solution Behavior and Self-Assembly in Nonpolar Solvents

2002 ◽  
Vol 35 (16) ◽  
pp. 6344-6350 ◽  
Author(s):  
Eugene A. Lysenko ◽  
Tatiana K. Bronich ◽  
Elena V. Slonkina ◽  
Adi Eisenberg ◽  
Victor A. Kabanov ◽  
...  
Keyword(s):  
Self Assembly ◽  
Solution Behavior ◽  
Selective Solvents ◽  
Nonpolar Solvents ◽  
Block Ionomer Complexes ◽  
Block Ionomer

New insights on the solution behavior and self-assembly of polystyrene/poly(2-vinylpyridine) ‘hairy’ heteroarm star copolymers with highly asymmetric arms in polar organic and aqueous media

Polymer ◽  
2005 ◽  
Vol 46 (23) ◽  
pp. 10493-10505 ◽  
Author(s):  
Miroslav Štěpánek ◽  
Pavel Matějíček ◽  
Jana Humpolíčková ◽  
Jitka Havránková ◽  
Klára Podhájecká ◽  
...  
Keyword(s):  
Self Assembly ◽  
Aqueous Media ◽  
Solution Behavior ◽  
Star Copolymers

Block Ionomer Complexes with Polystyrene Core-Forming Block in Selective Solvents of Various Polarities. 1. Solution Behavior and Self-Assembly in Aqueous Media

2002 ◽  
Vol 35 (16) ◽  
pp. 6351-6361 ◽  
Author(s):  
Eugene A. Lysenko ◽  
Tatiana K. Bronich ◽  
Elena V. Slonkina ◽  
Adi Eisenberg ◽  
Victor A. Kabanov ◽  
...  
Keyword(s):  
Self Assembly ◽  
Aqueous Media ◽  
Solution Behavior ◽  
Selective Solvents ◽  
Block Ionomer Complexes ◽  
Block Ionomer

scholarly journals Polyelectrolyte character of rigid rod peptide bundlemer chains constructed via hierarchical self-assembly

Soft Matter ◽  
2019 ◽  
Vol 15 (48) ◽  
pp. 9858-9870 ◽  
Author(s):  
Nairiti J. Sinha ◽  
Dongdong Wu ◽  
Christopher J. Kloxin ◽  
Jeffery G. Saven ◽  
Grethe V. Jensen ◽  
...  
Keyword(s):  
Self Assembly ◽  
Solution Behavior ◽  
Rigid Rods ◽  
Rich Solution ◽  
Rigid Rod

Hybrid physical-covalent assembly of computationally-designed bundlemers yields polyelectrolyte-like rigid rods displaying rich solution behavior.

scholarly journals Synthesis, aqueous solution behavior and self-assembly of a dual pH/thermo-responsive fluorinated diblock terpolymer

2021 ◽  
Author(s):  
Panagiotis G. Falireas ◽  
Vincent Ladmiral ◽  
Bruno Ameduri
Keyword(s):  
Aqueous Solution ◽  
Self Assembly ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Solution Behavior ◽  
Dual Responsive ◽  
Reversible Addition ◽  
Block Terpolymers

The synthesis of fluorinated dual-responsive block terpolymers via sequential reversible addition–fragmentation chain transfer (RAFT) polymerization is presented.

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