Copolymerization of Styrene and Methyl Methacrylate in the Presence of a Catalytic Chain Transfer Agent

1998 ◽  
Vol 31 (9) ◽  
pp. 2894-2905 ◽  
Author(s):  
Johan P. A. Heuts ◽  
Dax Kukulj ◽  
Darren J. Forster ◽  
Thomas P. Davis
Keyword(s):  
Methyl Methacrylate ◽  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Catalytic Chain Transfer

Catalytic Chain Transfer in a Miniemulsion Copolymerization of Methyl Methacrylate andn-Butyl Acrylate

2003 ◽  
Vol 36 (25) ◽  
pp. 9271-9274 ◽  
Author(s):  
Sebastiaan C. J. Pierik ◽  
Bart Smeets ◽  
Alex M. van Herk
Keyword(s):  
Methyl Methacrylate ◽  
Butyl Acrylate ◽  
Chain Transfer ◽  
Catalytic Chain Transfer

scholarly journals Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO2

2021 ◽  
Author(s):  
Ana A. C. Pacheco ◽  
Arnaldo F. da Silva Filho ◽  
Kristoffer Kortsen ◽  
Magnus W. D. Hanson-Heine ◽  
Vincenzo Taresco ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Methyl Methacrylate ◽  
Chain Transfer ◽  
Good Control ◽  
Chain Transfer Agent ◽  
Methylpropionic Acid ◽  
Transfer Agents

RAFT dispersion polymerisation of methyl methacrylate is performed in scCO2 with 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid (DDMAT) present as chain transfer agent (CTA) and surprisingly shows good control over PMMA molecular weight.

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