Semicrystalline Polymers via Ring-Opening Polymerization:  Preparation and Polymerization of Alkylene Phthalate Cyclic Oligomers

1998 ◽  
Vol 31 (15) ◽  
pp. 4782-4790 ◽  
Author(s):  
Daniel J. Brunelle ◽  
Jean E. Bradt ◽  
Judith Serth-Guzzo ◽  
Tohru Takekoshi ◽  
Thomas L. Evans ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Semicrystalline Polymers ◽  
Cyclic Oligomers

Synthesis and Ring-Opening Polymerization of Poly(alkylene 2,6-naphthalenedicarboxylate) Cyclic Oligomers

1996 ◽  
Vol 29 (26) ◽  
pp. 8304-8307 ◽  
Author(s):  
Patricia Hubbard ◽  
William J. Brittain ◽  
William J. Simonsick ◽  
Charles W. Ross
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Cyclic Oligomers

Preparation of crystalline and solvent resistant polycarbonates via ring-opening polymerization of cyclic oligomers

1994 ◽  
Vol 77 (1) ◽  
pp. 117-124 ◽  
Author(s):  
Daniel J. Brunelle ◽  
Herman O. Krabbenhoft ◽  
David K. Bonauto
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Cyclic Oligomers

Cyclic Aryl Ketone Oligomers Containing the Iso-Phthaloyl Moiety: Synthesis and Ring-Opening Polymerization

2013 ◽  
Vol 781-784 ◽  
pp. 411-414
Author(s):  
Li Song Hu ◽  
Jiang Yu Wu ◽  
Qing Zhong Guo
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Acylation Reaction ◽  
Excellent Thermal Stability ◽  
Cyclic Oligomers ◽  
Anionic Ring ◽  
Ether Ketone ◽  
Tof Ms ◽  
High Molecular Weight Poly ◽  
Aryl Ketone

Preparation of cyclic aryl ketone oligomers containing the iso-phthaloyl moiety by Friedel-Crafts acylation reaction is described. These cyclic oligomers are characterized by a combination of MALDI-TOF-MS and NMR analyses. The cyclic aryl ketone oligomers readily undergo anionic ring-opening polymerization in the melt by using potassium 4, 4-biphenoxide as the initiator, affording linear, high molecular weight poly (ether ketone) s with excellent thermal stability.

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