<p>Block copolymers are used to construct covalent adaptable networks that employ associative exchange chemistry (vitrimers). The resulting vitrimers display markedly different nanostructural, thermal and rheological properties relative to those of their statistical copolymer-derived counterparts. This study demonstrates that prepolymer sequence is a versatile strategy to modify the properties of vitrimers.</p>
A synthetic method for a series of poly(glycidol) (PG)-based amphiphilic block copolymers is presented with an emphasis on the catalyst switch method from an organic superbase (t-Bu-P4) to another with...
A series of reversible crosslinking assemblies with tunable morphologies are obtained from a new family of photoresponsive polypeptoid-based diblock copolymers.
A series of well-defined diblock copolymers containing PMMA, PEMA and PBMA blocks were synthesized with narrow MWDs and high yields via anionic polymerization, while t-BuOK was selected as initiator in THF at 0 °C. .
AbstractPoly(styrene-block-methyl methacrylate)s were fully analyzed by liquid chromatography at the critical point of adsorption (LC-CC) and two-dimensional chromatography. Operating at chromatographic conditions corresponding to the critical points of the homopolymers polystyrene and poly(methyl methacrylate), the block lengths distributions for the different blocks of the block copolymers were determined quantitatively. Information on the amounts and molar mass distributions of homopolymers and coupling products that were identified in the samples as by-products was obtained by on-line coupled 2D chromatography. It was shown that a complete picture of the molecular heterogeneity of block copolymers can be obtained only when information from different chromatographic experiments is combined. Size exclusion chromatography alone is inappropriate for evaluating the molecular heterogeneity of such samples.
A series of amphiphilic polydimethylsiloxane-b-poly[tri(ethylene glycol) methyl ether methacrylate] (PDMS-b-PM3) diblock copolymers were prepared with varying PM3 compositions.
We present the facile synthesis and orthogonal functionalization of diblock copolymers consisting of two incompatible segments, i.e. primary amines and activated esters, and demonstrate their use as protein-repellent brush layers with multivalent biorecognition.
A controlled synthesis method of alkyl methacrylate block copolymers via living anionic polymerization at ambient temperature