Preparation of Hyperbranched Polyacrylates by Atom Transfer Radical Polymerization. 1. Acrylic AB* Monomers in “Living” Radical Polymerizations

Krzysztof Matyjaszewski; Scott G. Gaynor; Anthony Kulfan; Matthew Podwika

doi:10.1021/ma970359g

Preparation of Hyperbranched Polyacrylates by Atom Transfer Radical Polymerization. 1. Acrylic AB* Monomers in “Living” Radical Polymerizations

Macromolecules ◽

10.1021/ma970359g ◽

1997 ◽

Vol 30 (17) ◽

pp. 5192-5194 ◽

Cited By ~ 228

Author(s):

Krzysztof Matyjaszewski ◽

Scott G. Gaynor ◽

Anthony Kulfan ◽

Matthew Podwika

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Atom Transfer ◽

Living Radical Polymerizations ◽

Radical Polymerizations ◽

Hyperbranched Polyacrylates

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Kinetic Analysis of Controlled/“Living” Radical Polymerizations by Simulations. 2. Apparent External Orders of Reactants in Atom Transfer Radical Polymerization

Macromolecules ◽

10.1021/ma991651m ◽

2000 ◽

Vol 33 (5) ◽

pp. 1553-1559 ◽

Cited By ~ 51

Author(s):

Devon A. Shipp ◽

Krzysztof Matyjaszewski

Keyword(s):

Atom Transfer Radical Polymerization ◽

Kinetic Analysis ◽

Radical Polymerization ◽

Atom Transfer ◽

Living Radical Polymerizations ◽

Radical Polymerizations

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Controlling polymer structures by atom transfer radical polymerization and other controlled/living radical polymerizations

Macromolecular Symposia ◽

10.1002/masy.200390131 ◽

2003 ◽

Vol 195 (1) ◽

pp. 25-32 ◽

Cited By ~ 22

Author(s):

Krzysztof Matyjaszewski

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Atom Transfer ◽

Living Radical Polymerizations ◽

Radical Polymerizations

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Atom Transfer Radical Polymerization from Nanoparticles: A Tool for the Preparation of Well-Defined Hybrid Nanostructures and for Understanding the Chemistry of Controlled/“Living” Radical Polymerizations from Surfaces

Journal of the American Chemical Society ◽

10.1021/ja010235q ◽

2001 ◽

Vol 123 (31) ◽

pp. 7497-7505 ◽

Cited By ~ 395

Author(s):

Timothy von Werne ◽

Timothy E. Patten

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Hybrid Nanostructures ◽

Atom Transfer ◽

Living Radical Polymerizations ◽

Radical Polymerizations

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Preparation of hyperbranched polyacrylates by atom transfer radical polymerization, 4. The use of zero-valent copper

Macromolecular Rapid Communications ◽

10.1002/(sici)1521-3927(19981201)19:12<665::aid-marc665>3.0.co;2-v ◽

1998 ◽

Vol 19 (12) ◽

pp. 665-670 ◽

Cited By ~ 73

Author(s):

Krzysztof Matyjaszewski ◽

Jeffrey Pyun ◽

Scott G. Gaynor

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Atom Transfer ◽

Hyperbranched Polyacrylates

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Preparation of Hyperbranched Polyacrylates by Atom Transfer Radical Polymerization. 2. Kinetics and Mechanism of Chain Growth for the Self-Condensing Vinyl Polymerization of 2-((2-Bromopropionyl)oxy)ethyl Acrylate

Macromolecules ◽

10.1021/ma970634z ◽

1997 ◽

Vol 30 (23) ◽

pp. 7034-7041 ◽

Cited By ~ 130

Author(s):

Krzysztof Matyjaszewski ◽

Scott G. Gaynor ◽

Axel H. E. Müller

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Ethyl Acrylate ◽

Kinetics And Mechanism ◽

The Self ◽

Chain Growth ◽

Atom Transfer ◽

Vinyl Polymerization ◽

Hyperbranched Polyacrylates

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Preparation of Hyperbranched Polyacrylates by Atom Transfer Radical Polymerization. 3. Effect of Reaction Conditions on the Self-Condensing Vinyl Polymerization of 2-((2-Bromopropionyl)oxy)ethyl Acrylate

Macromolecules ◽

10.1021/ma970635r ◽

1997 ◽

Vol 30 (23) ◽

pp. 7042-7049 ◽

Cited By ~ 111

Author(s):

Krzysztof Matyjaszewski ◽

Scott G. Gaynor

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Ethyl Acrylate ◽

The Self ◽

Atom Transfer ◽

Reaction Conditions ◽

Vinyl Polymerization ◽

Hyperbranched Polyacrylates

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ESR Study of Radicals in Conventional Radical Polymerizations Using Model Radicals Generated from Polymers Prepared by Atom Transfer Radical Polymerization

KOBUNSHI RONBUNSHU ◽

10.1295/koron.61.237 ◽

2004 ◽

Vol 61 (4) ◽

pp. 237-249 ◽

Cited By ~ 2

Author(s):

Atsushi KAJIWARA

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Atom Transfer ◽

Radical Polymerizations

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Controlling the Degree of Branching in Atom-Transfer Radical Polymerization of Hyperbranched Polyacrylates

Macromolecular Rapid Communications ◽

10.1002/1521-3927(20011101)22:16<1319::aid-marc1319>3.0.co;2-z ◽

2001 ◽

Vol 22 (16) ◽

pp. 1319-1324 ◽

Cited By ~ 11

Author(s):

Seung Hoo Yoo ◽

Tae Hee Yoon ◽

Jae Young Jho

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Atom Transfer ◽

Degree Of Branching ◽

Hyperbranched Polyacrylates

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Synthesis of Hyperbranched Polyacrylates in Emulsion by Atom Transfer Radical Polymerization

Macromolecules ◽

10.1021/ma011467c ◽

2002 ◽

Vol 35 (4) ◽

pp. 1146-1148 ◽

Cited By ~ 17

Author(s):

Seung Hoo Yoo ◽

Jun Hyup Lee ◽

Jong-Chan Lee ◽

Jae Young Jho

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Atom Transfer ◽

Hyperbranched Polyacrylates

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Living Radical Polymerizations of Methyl Methacrylate Mediated by Tris-(4-Carboxyphenyl) Methane

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.631-632.3 ◽

2013 ◽

Vol 631-632 ◽

pp. 3-8

Author(s):

Yuan Qing Xu ◽

Xiao Min Fang ◽

Tao Ding ◽

Yan Rong Ren

Keyword(s):

Methyl Methacrylate ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Linear Increase ◽

Living Radical Polymerization ◽

Chain Extension ◽

Atom Transfer ◽

Living Radical Polymerizations ◽

Effects Of Temperature ◽

Linear Kinetic

Pseudo-living radical polymerization and reverse atom transfer radical polymerization (RATRP) of methyl methacrylate (MMA) were reported, utilizing tris-(4-carboxyphenyl)methane (TCOPM) as the thermal iniferter and initiator, respectively. The polymerization of MMA using TCOPM as thermal iniferter possesses pseudo-living characteristics: Mn increases with conversion in a certain range, and the resulted polymer can be used as the macro-initiator for chain extension. The RATRP using TCOPM as the initiator shows linear kinetic plot, linear increase of Mn with conversion and narrow polydispersity indice (PDI) of the resultant polymers. Effects of temperature on both polymerizations were investigated.

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