Monte Carlo Simulation of Kinetics and Chain Length Distributions in Living Free-Radical Polymerization

1997 ◽  
Vol 30 (25) ◽  
pp. 8010-8018 ◽  
Author(s):  
Junpo He ◽  
Hongdong Zhang ◽  
Jingming Chen ◽  
Yuliang Yang
Keyword(s):  
Monte Carlo Simulation ◽  
Monte Carlo ◽  
Free Radical ◽  
Radical Polymerization ◽  
Chain Length ◽  
Free Radical Polymerization ◽  
Living Free Radical Polymerization

The Kinetics of Free-Radical Polymerization: Fundamental Aspects

2002 ◽  
Vol 55 (7) ◽  
pp. 399 ◽  
Author(s):  
G. T. Russell
Keyword(s):  
Molecular Weight ◽  
Steady State ◽  
Free Radical ◽  
Radical Polymerization ◽  
Chain Length ◽  
Free Radical Polymerization ◽  
Length Dependence ◽  
Model Independent ◽  
Living Free Radical Polymerization ◽  
Kinetics Of

Some fundamental aspects of the kinetics of free-radical polymerization are reviewed. So-called classical results for rate and molecular-weight distribution are first of all presented. It is shown how this approach can be built upon when chain-length-dependent termination is allowed, which it always should be. Various termination models are considered, and it is illustrated that although the models are different, rather remarkably they give common, model-independent behaviour. Some leading experimental results regarding the chain-length dependence of termination are summarized, before the chain-length dependence of other reactivities, the variation of reactivities with conversion, and non-steady state experiments are briefly discussed. Finally, living free-radical polymerization as effected by a reversible termination agent is considered. An outline of the kinetics of these systems is given, with the oft-neglected importance of conventional termination being stressed.

Living free radical polymerization (RAFT) of dodecyl acrylate: Chain length dependent termination, mid-chain radicals and monomer reaction order

Polymer ◽  
2005 ◽  
Vol 46 (18) ◽  
pp. 6797-6809 ◽  
Author(s):  
Alexander Theis ◽  
Achim Feldermann ◽  
Nathalie Charton ◽  
Thomas P. Davis ◽  
Martina H. Stenzel ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Chain Length ◽  
Reaction Order ◽  
Free Radical Polymerization ◽  
Living Free Radical Polymerization

Monte Carlo simulation of free radical polymerization of styrene in a spinning disc reactor

2014 ◽  
Vol 247 ◽  
pp. 231-240 ◽  
Author(s):  
Yousef Mohammadi ◽  
Amir Saeid Pakdel ◽  
Mohammad Reza Saeb ◽  
Kamelia Boodhoo
Keyword(s):  
Monte Carlo Simulation ◽  
Monte Carlo ◽  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Spinning Disc

scholarly journals Monte Carlo simulation on kinetics of batch and semi-batch free radical polymerization

2015 ◽  
Vol 23 (11) ◽  
pp. 1042-1050 ◽  
Author(s):  
Jing Shao ◽  
Wei Tang ◽  
Ru Xia ◽  
Xiaoshuang Feng ◽  
Peng Chen ◽  
...  
Keyword(s):  
Monte Carlo Simulation ◽  
Monte Carlo ◽  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Kinetics Of
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