Anionic Polymerization of Monomers Containing Functional Groups. 8. Anionic Living Polymerization of 4-Cyano-α-methylstyrene

1997 ◽  
Vol 30 (4) ◽  
pp. 757-763 ◽  
Author(s):  
Takashi Ishizone ◽  
Yukiko Okazawa ◽  
Kenji Ohnuma ◽  
Akira Hirao ◽  
Seiichi Nakahama
1992 ◽  
Vol 25 (19) ◽  
pp. 4840-4847 ◽  
Author(s):  
Takashi Ishizone ◽  
Junji Tsuchiya ◽  
Akira Hirao ◽  
Seiichi Nakahama

1991 ◽  
Vol 24 (18) ◽  
pp. 5015-5022 ◽  
Author(s):  
Takashi Ishizone ◽  
Sumio Wakabayashi ◽  
Akira Hirao ◽  
Seiichi Nakahama

1992 ◽  
Vol 25 (18) ◽  
pp. 4457-4463 ◽  
Author(s):  
Sunil K. Varshney ◽  
Robert Jerome ◽  
Philippe Bayard ◽  
Christian Jacobs ◽  
Roger Fayt ◽  
...  

1991 ◽  
Vol 64 (3) ◽  
pp. 450-468 ◽  
Author(s):  
Roderic P. Quirk ◽  
Jungahn Kim

Abstract A variety of living polymerization systems are now available for the controlled synthesis of block copolymers. Although living anionic polymerization remains as the method of choice for the most precise structural control, living polymerizations proceeding via other mechanistic types provide extremely useful extensions of this methodology to a wider variety of monomers.


1981 ◽  
Vol 54 (3) ◽  
pp. 627-640 ◽  
Author(s):  
Adel F. Halasa

Abstract In summary, one can say that the versatility of living polymerization makes it a very useful and unique technique. Synthetic polymer chemists can utilize the lithium at the end of the chain to add polymer-like conjugated monomers, in order to tailor-make the polymer chain, or they can use chelating diamines to change the microstructure of the polymer chain. They can also run hydrogenation on anionically prepared polydienes to produce thermoplastic elastomers. They can transform anionically made polymer chain ends by adding ethylene oxide, carbon dioxide and halogens. This paper has emphasized recent advances in this field.


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