Chain Transfer Activity of ω-Unsaturated Methyl Methacrylate Oligomers

1996 ◽  
Vol 29 (24) ◽  
pp. 7717-7726 ◽  
Author(s):  
Catherine L. Moad ◽  
Graeme Moad ◽  
Ezio Rizzardo ◽  
San H. Thang
Keyword(s):  
Methyl Methacrylate ◽  
Chain Transfer ◽  
Transfer Activity

Methyl methacrylate polymerization involving a cobalt ortho-iminobenzosemiquinone complex: Determination of the chain transfer constant

2015 ◽  
Vol 56 (3) ◽  
pp. 267-275 ◽  
Author(s):  
E. V. Kolyakina ◽  
Yu. E. Ovchinnikova ◽  
I. D. Grishin ◽  
A. I. Poddel’skii ◽  
D. F. Grishin
Keyword(s):  
Methyl Methacrylate ◽  
Chain Transfer ◽  
Transfer Constant ◽  
Methyl Methacrylate Polymerization ◽  
Chain Transfer Constant

Chain Transfer Activity of ω-Unsaturated Methacrylic Oligomers in Polymerizations of Methacrylic Monomers

2004 ◽  
Vol 37 (12) ◽  
pp. 4441-4452 ◽  
Author(s):  
Lillian Hutson ◽  
Julia Krstina ◽  
Catherine L. Moad ◽  
Graeme Moad ◽  
Gregory R. Morrow ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Transfer Activity ◽  
Methacrylic Monomers

Preparation of azobenzene-terminated polymers via reversible addition-fragmentation chain transfer (RAFT) polymerization

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Xiaoming Wan ◽  
Zhengbiao Zhang ◽  
Xiulin Zhu ◽  
Jian Zhu ◽  
Zhenping Cheng
Keyword(s):  
Methyl Methacrylate ◽  
Fluorescence Spectra ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Reversible Addition ◽  
Azobenzene Moiety

AbstractThree azobenzene-based dithiocarbamates, 2-(phenylazo-phenoxycarbonyl) prop-2-yl 9H-carbazole-9-carbodithioate (APCDT), 2-(4-nitro-phenylazophenoxy- carbonyl)prop-2-yl 9H-carbazole-9-carbodithioate (ANPCDT), 2-(4-cyanophenylazo- phenoxy-carbonyl)pro-2-yl 9H-carbazole-9-carbodithioate (ACPCDT), were synthesized and used as RAFT agents in the polymerizations of styrene (St) and methyl methacrylate (MMA). The results showed that APCDT, ACPCDT and ANPCDT were effective RAFT agents for the polymerization of St. In the case of MMA, the polymerization showed hybrid behavior. The different substitutes on azobenzene moiety in dithiocarbamates did not show obvious influence on the controllability of the polymerizations. The UV and fluorescence spectra of RAFT agents and obtained azobenzene-terminated polymers were investigated

Catalytic Chain Transfer in a Miniemulsion Copolymerization of Methyl Methacrylate andn-Butyl Acrylate

2003 ◽  
Vol 36 (25) ◽  
pp. 9271-9274 ◽  
Author(s):  
Sebastiaan C. J. Pierik ◽  
Bart Smeets ◽  
Alex M. van Herk
Keyword(s):  
Methyl Methacrylate ◽  
Butyl Acrylate ◽  
Chain Transfer ◽  
Catalytic Chain Transfer
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