scholarly journals Cross-Chain Transfer Rate Constants of Styrene-Terminated Radicals to Methyl Acrylate and Methyl Methacrylate

1996 ◽  
Vol 29 (21) ◽  
pp. 6717-6723 ◽  
Author(s):  
Harold A. S. Schoonbrood ◽  
Sebastiaan C. J. Pierik ◽  
Bram van den Reijen ◽  
Johan P. A. Heuts ◽  
Anton L. German
Keyword(s):  
Methyl Methacrylate ◽  
Methyl Acrylate ◽  
Rate Constants ◽  
Transfer Rate ◽  
Chain Transfer

Reversible addition-fragmentation chain transfer copolymerization of methyl methacrylate and methyl acrylate

2014 ◽  
Vol 87 (5) ◽  
pp. 640-645 ◽  
Author(s):  
B. N. Ionychev ◽  
Yu. D. Semchikov ◽  
N. A. Kopylova ◽  
E. S. Andreeva ◽  
S. D. Zaitsev
Keyword(s):  
Methyl Methacrylate ◽  
Methyl Acrylate ◽  
Chain Transfer ◽  
Reversible Addition

Absolute rate constants for hydrocarbon autoxidation. XVII. The oxidation of some cyclic ethers

1969 ◽  
Vol 47 (20) ◽  
pp. 3809-3815 ◽  
Author(s):  
J. A. Howard ◽  
K. U. Ingold
Keyword(s):  
Hydrogen Atom ◽  
Rate Constants ◽  
Transfer Rate ◽  
Chain Transfer ◽  
Hydrogen Atom Abstraction ◽  
Cyclic Ethers ◽  
Peroxy Radicals ◽  
Absolute Rate ◽  
Termination Rate

The propagation and termination rate constants have been determined for the autoxidation of 1,4-dioxan, tetrahydropyran, tetrahydrofuran, 2,5-dimethyltetrahydrofuran, and phthalan. The rate constants for α-hydrogen atom abstraction from some of the ethers by the tetralylperoxy radical and from tetralin by some ether peroxy radicals have been measured and compared. The chain transfer rate constants have been estimated for the reaction of the cumylperoxy radical with α-hydroperoxytetrahydrofuran, α-hydroperoxytetrahydropyran, and α-ethoxyethyl hydroperoxide.

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