A Novel Approach for the Chemical Recycling of Polymeric Materials:  The Network Polymer ⇄ Bifunctional Monomer Reversible System

1996 ◽  
Vol 29 (9) ◽  
pp. 3315-3316 ◽  
Author(s):  
Takeshi Endo ◽  
Takashi Suzuki ◽  
Fumio Sanda ◽  
Toshikazu Takata
Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1900
Author(s):  
Ramin Hosseinnezhad ◽  
Iurii Vozniak ◽  
Fahmi Zaïri

The paper discusses the possibility of using in situ generated hybrid polymer-polymer nanocomposites as polymeric materials with triple shape memory, which, unlike conventional polymer blends with triple shape memory, are characterized by fully separated phase transition temperatures and strongest bonding between the polymer blends phase interfaces which are critical to the shape fixing and recovery. This was demonstrated using the three-component system polylactide/polybutylene adipateterephthalate/cellulose nanofibers (PLA/PBAT/CNFs). The role of in situ generated PBAT nanofibers and CNFs in the formation of efficient physical crosslinks at PLA-PBAT, PLA-CNF and PBAT-CNF interfaces and the effect of CNFs on the PBAT fibrillation and crystallization processes were elucidated. The in situ generated composites showed drastically higher values of strain recovery ratios, strain fixity ratios, faster recovery rate and better mechanical properties compared to the blend.


1989 ◽  
Vol 43 (8) ◽  
pp. 1387-1393 ◽  
Author(s):  
William F. McDonald ◽  
Hans Goeitler ◽  
Marek W. Urban

A new rheo-photoacoustic Fourier transform infrared cell has been developed to perform stress-strain studies on polymeric materials. The rheo-photoacoustic measurements lead to the enhancement of the photoacoustic signal and allow one to monitor the effect of elongational forces on the molecular structure of polymers. Propagating acoustic waves are detected as a result of the deformational changes and thermal property changes upon the applied stress. Applications of this technique to fibers, films, and adhesion of thin films are presented.


2020 ◽  
Vol 8 (30) ◽  
pp. 15034-15041
Author(s):  
Ambavaram Vijaya Bhaskar Reddy ◽  
Muhammad Moniruzzaman ◽  
Mohamad A. Bustam ◽  
Masahiro Goto ◽  
Bidyut B. Saha ◽  
...  

Micelles are formed using a CO2-philic surfactant (N-ethyl perfluorooctyl sulfonamide) and embedded in in situ formed polymeric materials (SMI-ILPs) to enhance CO2 sorption.


2020 ◽  
pp. 0734242X2093674
Author(s):  
Amer Inayat ◽  
Katerina Klemencova ◽  
Barbora Grycova ◽  
Barbora Sokolova ◽  
Pavel Lestinsky

Thermo-catalytic pyrolysis is considered as a promising process for the chemical recycling of waste polymeric materials aiming at converting them into their original monomers or other valuable chemicals. In this regard, process parameters and reactor type can play important roles for an enhanced recovery of the desired products. Polystyrene (PS) wastes are excellent feedstocks for the chemical recycling owing to the capability of PS to be fully recycled. In this respect, the present work deals with the thermo-catalytic pyrolysis of PS in batch and semi-batch reactor setups. The main goal was to perform a comprehensive study on the depolymerisation of PS, thereby investigating the effect of reactor type, catalyst arrangement, feed to catalyst ratio and residence time on the yields of oil and styrene monomer (SM). A further goal was to identify the optimum operating conditions as well as reactor type for an enhanced recovery of oil and SM. It was demonstrated that the semi-batch reactor outperformed the batch reactor in terms of oil and SM yields in both thermal (non-catalytic) and catalytic tests performed at 400°C. Furthermore, it was shown that the layered arrangement of catalyst (catalyst separated from PS) produced a higher amount of oil with higher selectivity for SM as compared to the mixed arrangement (catalyst mixed with PS). Moreover, the effect of carrier gas flowrate on the product distribution was presented.


2015 ◽  
Vol 1767 ◽  
pp. 121-125
Author(s):  
Miguel Aguilar Cortes ◽  
Martha Lilia Domínguez Patiño ◽  
Antonio Rodríguez Martínez

ABSTRACTIn recent decades, we have seen an increase in the use of computers. This presents a crossroads in deciding what to do with the units that become "obsolete". As society, we have created a new type of solid waste that must be handled differently because the diversity of materials composition. In addition, at the end of their life cycle also affects the environment when the materials are disposal in landfill; i.e. plastic substrate (polycarbonate), may lead to chronic problems such as hyperactivity, infertility or even cancer.The recycling of electronic equipment is from whole parts, such as the electronic cables. Recover substances (plastics) and compounds (metals) from electronic cables could it be possible.We are looking for a solution to this problem and we created a structure of recycling to reduce the waste at the source and allows that which cannot be reduced is recycled, because computers contain 20% of thermoplastics and 6% of plastic mixtures that are the subject of this investigation.The recycled chemist hired himself since it provides capabilities that address the limitations of the mechanical recycling; you need large quantities of clean, separate, homogeneous plastic waste to be able to guarantee the quality of the final product. Chemical recycling overcomes these drawbacks, since the classification of the different types of plastic resins from of waste is not necessary.Based on the data obtained from this research, determines that the recycling of computer waste in conjunction with other plans of reduction at source makes this a viable alternative for the management of the same. Benefits that can be derived by establishing a recycling of the computer waste program is donating units or sell these affordable to low-income people who otherwise would not have access to this technology.


Author(s):  
Evgeniіa Mykhailova ◽  
Dmytro Deineka ◽  
Hanna Pancheva

Methods of plastic waste management, the amount of which is constantly growing due to the high demand for polymer products with high performance properties, are considered. The urgency of the problem is explained by longevity of plastic, which, once in the environment, gradually degrades with the formation of substances dangerous to living organisms. The most common ways of plastic waste management are its storage on specially designated land plots or incineration with / without getting heat. Each of these methods has certain disadvantages, which necessitates the introduction of other measures. Recycling of plastic waste into secondary raw materials, energy or products with certain consumer properties can be the promising method of plastic waste management from ecological and economic points of view. The purpose of this work is to analyze the methods of plastic waste recycling, to establish their advantages and disadvantages, to determine the optimal ways for the disposal of polymeric materials with different properties. Two main groups of polymer recycling methods: physical and chemical, are considered. Physical method includes mechanical recycling, which is based on the physical grinding of plastic waste to obtain secondary raw materials without significant changes in the chemical structure of the material. This process is quite simple in terms of technical design, but requires careful sorting and cleaning of waste, and has limitations on the reuse of recycled material. Chemical recycling takes place through the processes of solvolysis (hydrolysis, glycolysis, alcoholysis) and conversion (pyrolysis, gasification). In this case, the plastic waste decomposes into the original molecules – monomers, from which it is possible to get a polymer product with the same properties. Chemical methods allow disposing of unsorted and contaminated polymeric materials many times without losing their quality. Thus, the introduction of the described methods will reduce the amount of plastic waste, turn them into valuable secondary raw materials and reduce using of natural resources used to obtain primary plastic materials.


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