Synthesis and Photophysical Properties of a Novel Water-Soluble, Calixarene-Containing Polymer

1996 ◽  
Vol 29 (2) ◽  
pp. 617-624 ◽  
Author(s):  
D. M. Gravett ◽  
J. E. Guillet
Keyword(s):  
Photophysical Properties ◽  
Water Soluble

Novel Water-Soluble Cyclotriphosphazene-Bodipy Conjugates: Synthesis, Characterization and Photophysical Properties

2019 ◽  
Vol 29 (5) ◽  
pp. 1143-1152 ◽  
Author(s):  
Seda Çetindere ◽  
Elif Okutan ◽  
Süreyya Oğuz Tümay ◽  
Serkan Yeşilot ◽  
Adem Kılıç
Keyword(s):  
Photophysical Properties ◽  
Water Soluble

Photophysical properties of novel water soluble fullerene derivatives

2001 ◽  
Vol 350 (3-4) ◽  
pp. 198-205 ◽  
Author(s):  
Sarah Foley ◽  
Susanna Bosi ◽  
Christain Larroque ◽  
Maurizio Prato ◽  
Jean-Marc Janot ◽  
...  
Keyword(s):  
Photophysical Properties ◽  
Water Soluble ◽  
Fullerene Derivatives

Highly‐Luminescent DTTA‐Appended Water‐Soluble Lanthanide Complexes of 4‐(Het)aryl‐2,2′‐bipyridines: Synthesis and Photophysical Properties

2019 ◽  
Vol 4 (20) ◽  
pp. 6377-6381 ◽  
Author(s):  
Alexey P. Krinochkin ◽  
Dmitry S. Kopchuk ◽  
Grigory A. Kim ◽  
Il'ya N. Ganebnykh ◽  
Igor S. Kovalev ◽  
...  
Keyword(s):  
Lanthanide Complexes ◽  
Photophysical Properties ◽  
Water Soluble

scholarly journals Water-soluble cyclometalated platinum(ii) and iridium(iii) complexes: synthesis, tuning of the photophysical properties, and in vitro and in vivo phosphorescence lifetime imaging

RSC Advances ◽  
2018 ◽  
Vol 8 (31) ◽  
pp. 17224-17236 ◽  
Author(s):  
Anastasia I. Solomatina ◽  
Shih-Hao Su ◽  
Maria M. Lukina ◽  
Varvara V. Dudenkova ◽  
Vladislav I. Shcheslavskiy ◽  
...  
Keyword(s):  
Photophysical Properties ◽  
Water Soluble ◽  
Iridium Complexes ◽  
Hypoxia Imaging ◽  
Phosphorescence Lifetime ◽  
Lifetime Imaging ◽  
Phosphorescence Lifetime Imaging

Novel water-soluble iridium complexes with sulfonated diphosphine allow in vitro and in vivo lifetime hypoxia imaging.

Water-soluble Sulfonated Phosphorus(v) Corrolazines and Porphyrazines: Effect of Macrocycle Contraction and Pyrazine Ring Fusion on Spectral, Acid-base and Photophysical Properties

2021 ◽  
Author(s):  
Svetlana S. Ivanova ◽  
Denis S Salnikov ◽  
Gleb Knorr ◽  
Olesja Ledovich ◽  
Valery Sliznev ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Photophysical Properties ◽  
Water Soluble ◽  
Acid Base ◽  
Ring Fusion ◽  
Pyrazine Ring

Novel water-soluble dihydroxophosphorus(V) complexes of sulphophenyl substituted porphyrazine (6), corrolazine (7) and its pyrazine fused derivative (8) have been prepared and their spectral, acid-base and photophysical properties in aqueous solutions...

Synthesis and photophysical properties of a new cationic water-soluble Zn phthalocyanine

1997 ◽  
Vol 41 (3) ◽  
pp. 227-232 ◽  
Author(s):  
Daniel A. Fernández ◽  
Josefina Awruch ◽  
Lelia E. Dicelio
Keyword(s):  
Photophysical Properties ◽  
Water Soluble

scholarly journals Spectral properties and photophysical behaviour of water soluble cationic Mg(II) and Al(III) phthalocyanines

2014 ◽  
Vol 12 (3) ◽  
pp. 403-415 ◽  
Author(s):  
Mopelola Idowu ◽  
Yasin Arslanoğlu ◽  
Tebello Nyokong
Keyword(s):  
Aqueous Solution ◽  
Aqueous Medium ◽  
Spectral Properties ◽  
Photophysical Properties ◽  
Strong Dependence ◽  
Water Soluble ◽  
Quantum Yields ◽  
Fluorescence Lifetimes ◽  
High Solubility ◽  
Medium Ph

AbstractPeripherally and non-peripherally tetrasubstituted-[(N-methyl-2-pyridylthio)]phthalocyaninato magnesium (II) (5 and 6) and chloro aluminium (III) (7 and 8) tetraiodide have been synthesized and characterized. The photophysical properties of the complexes in dimethyl sulfoxide (DMSO) and aqueous medium in the presence and absence of cremophore EL have been studied. These complexes show high solubility in aqueous medium though they were aggregated. The triplet state quantum yields (FT) and the triplet lifetimes (tT) were found to be higher in DMSO with ΦT ranging from 0.32 to 0.51, while tT ranged from 282 to 622 ms in DMSO, compared to aqueous medium (pH 7.4 buffer) where ΦT ranged from 0.15 to 0.19 and tT from 26 to 35 ms. Addition of cremophore EL in aqueous solution resulted in partial disaggregation and increased photoactivity. The fluorescence lifetimes of the complexes showed strong dependence on their immediate environment. The ionic magnesium(II) and aluminium(III) phthalocyanines strongly bind to bovine serum albumin (BSA).

Effect of aggregation of a cationic phthalocyanine in micelles and in the presence of human serum albumin

2006 ◽  
Vol 10 (01) ◽  
pp. 33-42 ◽  
Author(s):  
Myriam E. Rodriguez ◽  
Daniel A. Fernández ◽  
Josefina Awruch ◽  
Silvia E. Braslavsky ◽  
Lelia E. Dicelio
Keyword(s):  
Human Serum Albumin ◽  
Serum Albumin ◽  
Human Serum ◽  
Hydrophobic Interactions ◽  
Photophysical Properties ◽  
Sodium Dodecylsulfate ◽  
Water Soluble ◽  
Quantum Yields ◽  
Ionic Interactions ◽  
Triplet Quantum Yields

The photophysical properties of tetrakis(1,1-dimethyl-2-trimethylammonium)ethylphthalocyaninato zinc(II) tetraiodide (I) – a water-soluble cationic phthalocyanine – are presented in the presence of human serum albumin (HSA) and in micelles of sodium dodecylsulfate ( SDS ) and hexadecyltrimethylammonium chloride ( CTAC ). Spectrophotometric measurements showed that the surfactants SDS and CTAC induce monomerization of I, although the latter less efficiently than the former. This effect is less pronounced in the presence of HSA. The strength of this effect is evaluated through dimerization constants, which are Kd = (5 ± 1) × 105 m−1 in SDS , (1.5 ± 0.5) × 106 M −1 in CTAC , and (1.8 ± 0.9) × 106 M −1 in HSA. Fluorescence experiments confirm that aggregation of I drops as the concentration of surfactant is raised. Triplet quantum yields also decreased upon aggregation and were Φ T = 0.59, 0.16, and < 0.01 in SDS , CTAC , and HSA, respectively. These results indicate that the affinity of I for the environment is not just due to ionic interactions; hydrophobic interactions play an equally important role.

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