Smart “All Acrylate” ABA Triblock Copolymer Bearing Reactive Functionality via Atom Transfer Radical Polymerization (ATRP): Demonstration of a “Click Reaction” in Thermoreversible Property

2010 ◽  
Vol 43 (7) ◽  
pp. 3193-3205 ◽  
Author(s):  
A. Amalin Kavitha ◽  
Nikhil K. Singha
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Triblock Copolymer ◽  
Click Reaction ◽  
Atom Transfer ◽  
Aba Triblock Copolymer

Synthesis of Triblock Copolymer Brushes by Surface-Initiated Atom Transfer Radical Polymerization

2002 ◽  
Vol 35 (14) ◽  
pp. 5410-5416 ◽  
Author(s):  
Jong-Bum Kim ◽  
Wenxi Huang ◽  
Merlin L. Bruening ◽  
Gregory L. Baker
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Triblock Copolymer ◽  
Atom Transfer ◽  
Copolymer Brushes

Novel Chemoenzymatic Synthesis of Triblock Copolymer

2011 ◽  
Vol 396-398 ◽  
pp. 2459-2462
Author(s):  
Xiao Tian Liu ◽  
Hong Bo Fan
Keyword(s):  
Block Copolymer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Triblock Copolymer ◽  
Sebacic Acid ◽  
Ring Opening Polymerization ◽  
Chemoenzymatic Synthesis ◽  
Atom Transfer ◽  
Novozyme 435

Enzymatic polycondensation of benzyl-2,2-bis(methylol) propionate and sebacic acid has been performed using lipase Novozyme-435 as the catalyst, subsequently enzymatic ring-opening polymerization was reacted by adding ε-caprolactone as the monomer in the same system. Then atom transfer radical polymerization (ATRP) from the macroinitiator combining α-bromoester of styrene was catalyzed by CuCl/2,2’-Dipyridyl to obtain the block copolymer successfully. The polymers obtained in different conditions were analyzed by 1HNMR and GPC.

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