An Exploration of the Effects of Reversibility in Chain Transfer to Metal in Olefin Polymerization

Phillip D. Hustad; Roger L. Kuhlman; Edmund M. Carnahan; Timothy T. Wenzel; Daniel J. Arriola

doi:10.1021/ma800357n

An Exploration of the Effects of Reversibility in Chain Transfer to Metal in Olefin Polymerization

Macromolecules ◽

10.1021/ma800357n ◽

2008 ◽

Vol 41 (12) ◽

pp. 4081-4089 ◽

Cited By ~ 61

Author(s):

Phillip D. Hustad ◽

Roger L. Kuhlman ◽

Edmund M. Carnahan ◽

Timothy T. Wenzel ◽

Daniel J. Arriola

Keyword(s):

Chain Transfer ◽

Olefin Polymerization

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Magnesium chloride supported high-mileage catalyst for olefin polymerization. IX. Molecular weight and distribution and chain-transfer processes

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.1986.080240805 ◽

1986 ◽

Vol 24 (8) ◽

pp. 1779-1818 ◽

Cited By ~ 16

Author(s):

James C. W. Chien ◽

Chi-I. Kuo

Keyword(s):

Molecular Weight ◽

Magnesium Chloride ◽

Chain Transfer ◽

Olefin Polymerization ◽

Transfer Processes

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Borane chain transfer reaction in olefin polymerization using trialkylboranes as chain transfer agents

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/pola.24125 ◽

2010 ◽

Vol 48 (16) ◽

pp. 3534-3541 ◽

Cited By ~ 24

Author(s):

Wentian Lin ◽

Hui Niu ◽

T. C. Mike Chung ◽

Jin-Yong Dong

Keyword(s):

Transfer Reaction ◽

Chain Transfer ◽

Olefin Polymerization ◽

Chain Transfer Reaction ◽

Transfer Agents

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Marked Counteranion Effects on Single-Site Olefin Polymerization Processes. Correlations of Ion Pair Structure and Dynamics with Polymerization Activity, Chain Transfer, and Syndioselectivity

Journal of the American Chemical Society ◽

10.1021/ja036288k ◽

2004 ◽

Vol 126 (14) ◽

pp. 4605-4625 ◽

Cited By ~ 98

Author(s):

Ming-Chou Chen ◽

John A. S. Roberts ◽

Tobin J. Marks

Keyword(s):

Chain Transfer ◽

Olefin Polymerization ◽

Ion Pair ◽

Single Site ◽

Structure And Dynamics ◽

Activity Chain

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Unsaturated Alcohols as Chain-Transfer Agents in Olefin Polymerization: Synthesis of Aldehyde End-Capped Oligomers and Polymers

Journal of the American Chemical Society ◽

10.1021/jacs.0c06644 ◽

2020 ◽

Vol 142 (36) ◽

pp. 15431-15437 ◽

Cited By ~ 1

Author(s):

Xing-Wang Han ◽

Olafs Daugulis ◽

Maurice Brookhart

Keyword(s):

Chain Transfer ◽

Olefin Polymerization ◽

Unsaturated Alcohols ◽

Transfer Agents

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Borane Chain Transfer Agent in Metallocene-Mediated Olefin Polymerization. Synthesis of Borane-Terminated Polyethylene and Diblock Copolymers Containing Polyethylene and Polar Polymer

Journal of the American Chemical Society ◽

10.1021/ja9913232 ◽

1999 ◽

Vol 121 (28) ◽

pp. 6763-6764 ◽

Cited By ~ 78

Author(s):

Guangxue Xu ◽

T. C. Chung

Keyword(s):

Diblock Copolymers ◽

Chain Transfer ◽

Olefin Polymerization ◽

Chain Transfer Agent ◽

Polar Polymer

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Suppression of Chain Transfer via Restricted Rotation Effect of Dibenzosuberyl Substituents in Polymerization Catalysis

Polymer Chemistry ◽

10.1039/d1py00333j ◽

2021 ◽

Author(s):

Shengyu Dai ◽

Gen Li ◽

Weiqing Lu ◽

Yudan Liao ◽

Weigang Fan

Keyword(s):

Chain Transfer ◽

Olefin Polymerization ◽

Effective Strategy ◽

Rotation Effect ◽

Restricted Rotation ◽

Polymerization Catalysis

The introduction of bulky ortho-steric substituents into α-diimine Ni(II) and Pd(II) species has been often used as an effective strategy to retard the chain transfer in olefin polymerization. In this...

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A Second Transition State for Chain Transfer to Monomer in Olefin Polymerization Promoted by Group 4 Metal Catalysts

Journal of the American Chemical Society ◽

10.1021/ja0586034 ◽

2006 ◽

Vol 128 (14) ◽

pp. 4524-4525 ◽

Cited By ~ 25

Author(s):

Giovanni Talarico ◽

Peter H. M. Budzelaar

Keyword(s):

Transition State ◽

Chain Transfer ◽

Olefin Polymerization ◽

Metal Catalysts ◽

Group 4 ◽

Group 4 Metal

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Special Issue on Recent Advances in Coordination Polymerization of Olefins. Chain Transfer Reactions in Olefin Polymerization with Ethylenebis(tetrahydroindenyl)zirconium Dichloride Combined with Methylalumoxane.

KOBUNSHI RONBUNSHU ◽

10.1295/koron.51.663 ◽

1994 ◽

Vol 51 (10) ◽

pp. 663-669 ◽

Cited By ~ 2

Author(s):

Takeshi SHIONO ◽

Toshiya UOZUMI ◽

Kazuo SOGA

Keyword(s):

Chain Transfer ◽

Olefin Polymerization ◽

Transfer Reactions ◽

Special Issue ◽

Coordination Polymerization ◽

Recent Advances

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Hydrogen chain transfer in olefin polymerization with organometallic catalysts

Journal of Polymer Science Polymer Chemistry Edition ◽

10.1002/pol.1978.170160920 ◽

1978 ◽

Vol 16 (9) ◽

pp. 2337-2342 ◽

Cited By ~ 3

Author(s):

George A. Mortimer ◽

Morris R. Ort ◽

Edward H. Mottus

Keyword(s):

Chain Transfer ◽

Olefin Polymerization ◽

Organometallic Catalysts

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Competitive Chain Transfer by .beta.-Hydrogen and .beta.-Methyl Elimination for a Model Ziegler-Natta Olefin Polymerization System [Me2Si(.eta.5-C5Me4)2]Sc{CH2CH(CH3)2}(PMe3)

Organometallics ◽

10.1021/om00016a018 ◽

1994 ◽

Vol 13 (4) ◽

pp. 1147-1154 ◽

Cited By ~ 60

Author(s):

Sharad Hajela ◽

John E. Bercaw

Keyword(s):

Chain Transfer ◽

Olefin Polymerization ◽

Polymerization System

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