Conformation of Block Copolymers in Dilute Solution. 3. Determination of the Center-to-Center Distance between the Two Blocks by Light Scattering

1979 ◽  
Vol 12 (1) ◽  
pp. 146-152 ◽  
Author(s):  
Takeshi Tanaka ◽  
Mitsuru Omoto ◽  
Hiroshi Inagaki
Keyword(s):  
Light Scattering ◽  
Block Copolymers ◽  
Dilute Solution ◽  
Center Distance

The effect of heterogeneity in composition on the determination of molecular weight distribution of block copolymers by gel permeation chromatography

1969 ◽  
Vol 22 (3) ◽  
pp. 543 ◽  
Author(s):  
JR Urwin ◽  
DN Cramond
Keyword(s):  
Molecular Weight ◽  
Light Scattering ◽  
Block Copolymers ◽  
Molecular Weight Distribution ◽  
Weight Distribution ◽  
Gel Permeation Chromatography ◽  
Scattering Data ◽  
Gel Permeation

The molecular weight of samples of block copolymers of poly(isoprene : styrene) determined by gel permeation chromatography (g.p.c.) are found to deviate from the values obtained by light scattering and osmometry. The extent of the deviation depends on composition, and comparision of (g.p.c.) values with osmometry (MN) can be interpreted if account is taken of the effect of heterogeneity. The drift in composition with molecular weight calculated from light scattering data can be used to predict the direction of the deviation, at least qualitatively.

Determination of the Micelle Architecture of Polystyrene/Poly(4-vinylpyridine) Block Copolymers in Dilute Solution

1994 ◽  
Vol 27 (12) ◽  
pp. 3276-3281 ◽  
Author(s):  
Markus Antonietti ◽  
Steffi Heinz ◽  
Manfred Schmidt ◽  
Christine Rosenauer
Keyword(s):  
Block Copolymers ◽  
Dilute Solution
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