Volume dependence of the elastic equation of state. 2. Solution-cured poly(dimethylsiloxane)

1981 ◽  
Vol 14 (5) ◽  
pp. 1445-1448 ◽  
Author(s):  
R. W. Brotzman ◽  
B. E. Eichinger
Keyword(s):  
Equation Of State ◽  
Volume Dependence

Volume dependence of the elastic equation of state. 3. Bulk-cured poly(dimethylsiloxane)

1982 ◽  
Vol 15 (2) ◽  
pp. 531-535 ◽  
Author(s):  
R. W. Brotzman ◽  
B. E. Eichinger
Keyword(s):  
Equation Of State ◽  
Volume Dependence

A New Isothermal Equation of State for Solids

2009 ◽  
Vol 64 (1-2) ◽  
pp. 54-58
Author(s):  
Quan Liu
Keyword(s):  
Equation Of State ◽  
Critical Analysis ◽  
Short Range ◽  
Rare Gas ◽  
Volume Data ◽  
Volume Dependence ◽  
Short Range Force ◽  
Good Accordance ◽  
Isothermal Equation ◽  
Range Force

A new isothermal equation of state (EOS) for solids is derived by starting from the theory of lattice potential and using an analytical function for the volume dependence of the short-range force constant. A critical analysis of the isothermal EOSs: Murnaghan EOS, Vinet EOS, and the new EOS derived here, is presented by investigating the pressure-volume data for rare gas solids, metals and minerals. It is found that the results obtained from the new EOS are in good accordance with the corresponding values obtained from the Vinet EOS and with experimental data for all the solids up to very large compressions. On the other hand, the Murnaghan EOS is less successful at high pressure in most cases.

Pressure dependence of the Grüneisen parameter and melting temperature of some metals

2021 ◽  
pp. 2150255
Author(s):  
K. Sunil ◽  
D. Ashwini ◽  
Vijay S. Sharma
Keyword(s):  
Experimental Data ◽  
Molecular Dynamics ◽  
Equation Of State ◽  
Pressure Dependence ◽  
High Pressures ◽  
Grüneisen Parameter ◽  
Thermal Equation ◽  
Gruneisen Parameter ◽  
Melting Temperatures ◽  
Volume Dependence

We have used a method for determining volume dependence of the Grüneisen parameter in the Lindemann law to study the pressure dependence of melting temperatures in case of 10 metals viz. Cu, Mg, Pb, Al, In, Cd, Zn, Au, Ag and Mn. The reciprocal gamma relationship has been used to estimate the values of Grüneisen parameters at different volumes. The results for melting temperatures of metals at high pressures obtained in this study using the Lindemann law of melting are compared with the available experimental data and also with the values calculated from the instability model based on a thermal equation of state. The analytical model used in this study is much simpler than the accurate DFT calculations and molecular dynamics.

Analysis of melting curves of MgO and LiF using the Lindemann law

2018 ◽  
Vol 32 (30) ◽  
pp. 1850339 ◽  
Author(s):  
K. Sunil ◽  
S. B. Sharma ◽  
B. S. Sharma
Keyword(s):  
Experimental Data ◽  
Equation Of State ◽  
Finite Difference ◽  
Bulk Modulus ◽  
Melting Temperature ◽  
Pressure Dependence ◽  
Grüneisen Parameter ◽  
Gruneisen Parameter ◽  
Melting Temperatures ◽  
Volume Dependence

We have determined the melting slopes as a function of pressure for MgO up to a pressure of 135 GPa, and for LiF up to a pressure of 100 GPa using the Lindemann law. Values of melting temperature have also been calculated from the melting slopes using Euler’s finite difference calculus method. It is found that the melting slope decreases continuously with the increase in pressure giving a nonlinear pressure dependence of the melting temperature. Values of bulk modulus and the Grüneisen parameter appearing in the Lindemann law of melting have been determined using the Stacey reciprocal K-primed equation of state and the Shanker reciprocal gamma relationship. The results for melting temperatures of MgO and LiF at different pressures are compared with the available experimental data. Values of melting temperatures at different pressures determined from the Al’tshuler relationship for the volume dependence of the Grüneisen parameter have also been included in the comparison presented.

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