Organotellurium-Mediated Living Radical Polymerization (TERP) of Acrylates Using Ditelluride Compounds and Binary Azo Initiators for the Synthesis of High-Performance Adhesive Block Copolymers for On-Demand Dismantlable Adhesion

2013 ◽  
Vol 46 (20) ◽  
pp. 8111-8120 ◽  
Author(s):  
Tadashi Inui ◽  
Keisuke Yamanishi ◽  
Eriko Sato ◽  
Akikazu Matsumoto
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
High Performance ◽  
Living Radical Polymerization ◽  
On Demand ◽  
Azo Initiators

High-molecular-weight polar acrylate block copolymers as high-performance dismantlable adhesive materials in response to photoirradiation and postbaking

RSC Advances ◽  
2014 ◽  
Vol 4 (47) ◽  
pp. 24719-24728 ◽  
Author(s):  
Tadashi Inui ◽  
Eriko Sato ◽  
Akikazu Matsumoto
Keyword(s):  
Molecular Weight ◽  
Block Copolymers ◽  
High Molecular Weight ◽  
Radical Polymerization ◽  
Failure Mode ◽  
Adhesion Strength ◽  
High Performance ◽  
Living Radical Polymerization ◽  
Controlled Synthesis ◽  
Adhesive Materials

Controlled synthesis of block copolymers as dismantlable adhesives using an organotellurium-mediated living radical polymerization (TERP) for discussion of adhesion strength and failure mode.

Synthesis of amphiphilic nanoparticles and multi-block hydrophilic copolymers by a facile and effective “living” radical polymerization in water

2016 ◽  
Vol 7 (14) ◽  
pp. 2486-2491 ◽  
Author(s):  
Juanjuan Wu ◽  
Hongjuan Jiang ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Robust Approach ◽  
Amphiphilic Nanoparticles

A convenient and robust approach using MANDC-COOH as the initiator and oxidatively stable Cu(OAc)2as the catalyst to synthesize amphiphilic nanoparticles and hydrophilic multi-block copolymers was successfully developed in water.

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