Ionic Transport, Microphase Separation, and Polymer Relaxation in Poly(propylene glycol) and Lithium Perchlorate Mixtures

2013 ◽  
Vol 46 (23) ◽  
pp. 9380-9389 ◽  
Author(s):  
Fei Fan ◽  
Yangyang Wang ◽  
Alexei P. Sokolov
Keyword(s):  
Propylene Glycol ◽  
Microphase Separation ◽  
Lithium Perchlorate ◽  
Ionic Transport ◽  
Polymer Relaxation ◽  
Poly Propylene

A comparison of acetone and poly(propylene glycol) as solvents for lithium triflate and lithium perchlorate

1991 ◽  
Vol 69 (12) ◽  
pp. 1980-1984 ◽  
Author(s):  
James R. Stevens ◽  
Per Jacobsson
Keyword(s):  
Propylene Glycol ◽  
Ion Pairs ◽  
Lithium Perchlorate ◽  
Lithium Triflate ◽  
Free Ions ◽  
Lower Dielectric Constant ◽  
Current Controversy ◽  
Raman Modes ◽  
Poly Propylene ◽  
Key Words Acetone

Solutions of LiCF3SO3 and LiClO4 in acetone and in poly(propylene glycol) (PPG 400 and PPG 4000) have been compared by studying the nondegenerate, symmetric stretch (A1,SO3) and (A1,ClO4) Raman modes. The Raman spectra contain bands due to the symmetric stretching motion of the "free" anion and due to the symmetric stretching motion of anions in ion aggregates. It is concluded that "free" ions, ion pairs, triplets, and aggregates are present. Although PPG has a much lower dielectric constant, it is a better solvent for these salts than the dipolar aprotic acetone. These findings have ramifications on the current controversy of whether "free" ions are present at all in polyether–salt complexes such as PPG 4000/LiCF3SO3. Key words: acetone, poly(propylene glycol), lithium triflate, lithium perchlorate, Raman.

Molecular dynamics of poly(propylene) glycol in nanometer confinements

2000 ◽  
Vol 10 (PR7) ◽  
pp. Pr7-271-Pr7-274 ◽  
Author(s):  
A. Schönhals ◽  
H. Goering ◽  
K.-W. Brzezinka ◽  
Ch. Schick
Keyword(s):  
Molecular Dynamics ◽  
Propylene Glycol ◽  
Poly Propylene

Equation of State of Hydrogen-Bonded Polymer Solutions. Poly(propylene glycol) +n-Hexane and Poly(propylene glycol) + Ethanol

1997 ◽  
Vol 30 (11) ◽  
pp. 3389-3394 ◽  
Author(s):  
Amalia Crespo Colin ◽  
Susana M. Cancho ◽  
Ramon G. Rubio ◽  
Aurora Compostizo
Keyword(s):  
Equation Of State ◽  
Propylene Glycol ◽  
Polymer Solutions ◽  
Poly Propylene ◽  
Hydrogen Bonded

Osteoconductivity of an injectable and bioresorbable poly(propylene glycol-co-fumaric acid) bone cement

Biomaterials ◽  
2000 ◽  
Vol 21 (3) ◽  
pp. 293-298 ◽  
Author(s):  
Kai-Uwe Lewandrowski ◽  
Joseph D Gresser ◽  
Donald L Wise ◽  
Roslyn L White ◽  
Debra J Trantolo
Keyword(s):  
Bone Cement ◽  
Propylene Glycol ◽  
Fumaric Acid ◽  
Poly Propylene
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