Solvent Effects on the Activation Rate Constant in Atom Transfer Radical Polymerization

Markus Horn; Krzysztof Matyjaszewski

doi:10.1021/ma400565k

Solvent Effects on the Activation Rate Constant in Atom Transfer Radical Polymerization

Macromolecules ◽

10.1021/ma400565k ◽

2013 ◽

Vol 46 (9) ◽

pp. 3350-3357 ◽

Cited By ~ 73

Author(s):

Markus Horn ◽

Krzysztof Matyjaszewski

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Rate Constant ◽

Solvent Effects ◽

Atom Transfer ◽

Activation Rate

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Thermodynamic Components of the Atom Transfer Radical Polymerization Equilibrium: Quantifying Solvent Effects

Macromolecules ◽

10.1021/ma901094s ◽

2009 ◽

Vol 42 (17) ◽

pp. 6348-6360 ◽

Cited By ~ 152

Author(s):

Wade A. Braunecker ◽

Nicolay V. Tsarevsky ◽

Armando Gennaro ◽

Krzysztof Matyjaszewski

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Solvent Effects ◽

Atom Transfer ◽

Polymerization Equilibrium

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Solvent Effects and Side Reactions in Organocatalyzed Atom Transfer Radical Polymerization for Enabling the Controlled Polymerization of Acrylates Catalyzed by Diaryl Dihydrophenazines

Macromolecules ◽

10.1021/acs.macromol.0c02245 ◽

2020 ◽

Vol 53 (21) ◽

pp. 9208-9219

Author(s):

Blaine McCarthy ◽

Steven Sartor ◽

Justin Cole ◽

Niels Damrauer ◽

Garret M. Miyake

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Solvent Effects ◽

Side Reactions ◽

Atom Transfer ◽

Controlled Polymerization

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Experimental Determination of the Rate Constant of Deactivation of Poly(styrene) and Poly(butyl acrylate) Radicals in Atom Transfer Radical Polymerization

Macromolecules ◽

10.1021/ma011623f ◽

2002 ◽

Vol 35 (9) ◽

pp. 3420-3425 ◽

Cited By ~ 24

Author(s):

Grégory Chambard ◽

Bert Klumperman ◽

Anton L. German

Keyword(s):

Atom Transfer Radical Polymerization ◽

Experimental Determination ◽

Radical Polymerization ◽

Rate Constant ◽

Butyl Acrylate ◽

Atom Transfer

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Determination of the activation rate constants of alkyl halide initiators for atom transfer radical polymerization

Macromolecular Rapid Communications ◽

10.1002/(sici)1521-3927(19991201)20:12<633::aid-marc633>3.0.co;2-2 ◽

1999 ◽

Vol 20 (12) ◽

pp. 633-636 ◽

Cited By ~ 45

Author(s):

Atsushi Goto ◽

Takeshi Fukuda

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Rate Constants ◽

Alkyl Halide ◽

Atom Transfer ◽

Activation Rate

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Effect of the Copper Counterion on the Activation Rate Parameter in Atom Transfer Radical Polymerization

Macromolecules ◽

10.1021/ma010803m ◽

2001 ◽

Vol 34 (23) ◽

pp. 7961-7966 ◽

Cited By ~ 22

Author(s):

Mike A. J. Schellekens ◽

Frank de Wit ◽

Bert Klumperman

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Atom Transfer ◽

Rate Parameter ◽

Activation Rate

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Effect of [PMDETA]/[Cu(I)] Ratio, Monomer, Solvent, Counterion, Ligand, and Alkyl Bromide on the Activation Rate Constants in Atom Transfer Radical Polymerization

Macromolecules ◽

10.1021/ma0340107 ◽

2003 ◽

Vol 36 (5) ◽

pp. 1487-1493 ◽

Cited By ~ 98

Author(s):

Ajaya Kumar Nanda ◽

Krzysztof Matyjaszewski

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Rate Constants ◽

Atom Transfer ◽

Alkyl Bromide ◽

Activation Rate

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Effect of Solvent on the Activation Rate Parameters for Polystyrene and Poly(butyl acrylate) Macroinitiators in Atom Transfer Radical Polymerization

Macromolecules ◽

10.1021/ma992153g ◽

2000 ◽

Vol 33 (12) ◽

pp. 4417-4421 ◽

Cited By ~ 52

Author(s):

Grégory Chambard ◽

Bert Klumperman ◽

Anton L. German

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Butyl Acrylate ◽

Atom Transfer ◽

Effect Of Solvent ◽

Activation Rate

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Solvent Effects on the Synthesis of Poly(methyl methacrylate) by Atom-Transfer Radical Polymerization (ATRP)

Macromolecular Chemistry and Physics ◽

10.1002/1521-3935(20010801)202:12<2565::aid-macp2565>3.0.co;2-4 ◽

2001 ◽

Vol 202 (12) ◽

pp. 2565-2571 ◽

Cited By ~ 30

Author(s):

José Luis de la Fuente ◽

Marina Fernández-Sanz ◽

Marta Fernández-García ◽

Enrique López Madruga

Keyword(s):

Methyl Methacrylate ◽

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Solvent Effects ◽

Atom Transfer ◽

Poly Methyl Methacrylate

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Effect of [bpy]/[Cu(I)] Ratio, Solvent, Counterion, and Alkyl Bromides on the Activation Rate Constants in Atom Transfer Radical Polymerization

Macromolecules ◽

10.1021/ma021418f ◽

2003 ◽

Vol 36 (3) ◽

pp. 599-604 ◽

Cited By ~ 63

Author(s):

Ajaya Kumar Nanda ◽

Krzysztof Matyjaszewski

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Rate Constants ◽

Atom Transfer ◽

Alkyl Bromides ◽

Activation Rate

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Solvent Effects on the Redox Properties of Cu Complexes Used as Mediators in Atom Transfer Radical Polymerization

The Journal of Physical Chemistry A ◽

10.1021/jp057191i ◽

2006 ◽

Vol 110 (34) ◽

pp. 10355-10360 ◽

Cited By ~ 11

Author(s):

Géraldine Coullerez ◽

Eva Malmström ◽

Mats Jonsson

Keyword(s):

Atom Transfer Radical Polymerization ◽

Radical Polymerization ◽

Solvent Effects ◽

Redox Properties ◽

Atom Transfer ◽

Cu Complexes

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