Amphiphilic ABC Triblock Copolymers Tailored via RAFT Polymerization as Textile Surface Modifiers with Dual-Action Properties

2013 ◽  
Vol 46 (7) ◽  
pp. 2616-2627 ◽  
Author(s):  
Martin Messerschmidt ◽  
Hartmut Komber ◽  
Liane Häußler ◽  
Christian Hanzelmann ◽  
Manfred Stamm ◽  
...  
2014 ◽  
Vol 50 (65) ◽  
pp. 9145-9148 ◽  
Author(s):  
Keren Zhang ◽  
Gregory B. Fahs ◽  
Motohiro Aiba ◽  
Robert B. Moore ◽  
Timothy E. Long

RAFT polymerization afforded acrylic ABC triblock copolymers with self-complementary nucleobase-functionalized external blocks and a low-Tg soft central block.


2007 ◽  
Vol 85 (6) ◽  
pp. 407-411 ◽  
Author(s):  
Ya Cao ◽  
X X Zhu

Reversible addition-fragmentation chain transfer (RAFT) polymerization of N-alkyl substituted acrylamides has been carried out by the use of a trithiocarbonate (2-dodecylsulfanylthiocarbonyl-sulfanyl-2-methyl propionic acid) as the RAFT reagent. The N-alkyl groups of the acrylamide monomers are important in the RAFT process. N-alkyl monosubstituted polyacrylamides are found to be active macro-chain transfer agents, while N,N-disubstituted monomers can react easily with them to form a sequent block. We have designed a synthetic pathway to successfully prepare ABC triblock copolymers of N-alkyl substituted acrylamides with low polydispersities (PDI < 1.20) by a three-step RAFT polymerization process.Key words: block copolymers, RAFT polymerization, N-alkyl substituted acrylamides, thermosensitive polymers.


2017 ◽  
Vol 9 (35) ◽  
pp. 30056-30063 ◽  
Author(s):  
Xin Zhou ◽  
Junhua Kong ◽  
Jiaotong Sun ◽  
Hui Li ◽  
Chaobin He

1998 ◽  
Vol 31 (22) ◽  
pp. 7756-7763 ◽  
Author(s):  
V. Balsamo ◽  
A. J. Müller ◽  
R. Stadler

2006 ◽  
Vol 39 (26) ◽  
pp. 9365-9374 ◽  
Author(s):  
Laurent Corté ◽  
Valéry Rebizant ◽  
Gilles Hochstetter ◽  
François Tournilhac ◽  
Ludwik Leibler

2009 ◽  
Vol 69 (9) ◽  
pp. 666-672 ◽  
Author(s):  
Xiaohua He ◽  
Liang Zhong ◽  
Kai Wang ◽  
Shaoliang Lin ◽  
Shufang Luo

2017 ◽  
Vol 50 (7) ◽  
pp. 2794-2802 ◽  
Author(s):  
Habib Khan ◽  
Shengli Chen ◽  
Heng Zhou ◽  
Shuang Wang ◽  
Wangqing Zhang

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