Processing–Morphology–Property Relationships and Composite Theory Analysis of Reduced Graphene Oxide/Natural Rubber Nanocomposites

2012 ◽  
Vol 45 (15) ◽  
pp. 6045-6055 ◽  
Author(s):  
Jeffrey R. Potts ◽  
Om Shankar ◽  
Ling Du ◽  
Rodney S. Ruoff
2020 ◽  
Vol 35 (5) ◽  
pp. 493-502
Author(s):  
F. Shahamatifard ◽  
D. Rodrigue ◽  
K. Park ◽  
S. Frikha ◽  
F. Mighri

2014 ◽  
Vol 6 (4) ◽  
pp. 2230-2234 ◽  
Author(s):  
Giuseppe Scherillo ◽  
Marino Lavorgna ◽  
Giovanna G. Buonocore ◽  
Yanhu H. Zhan ◽  
Hesheng S. Xia ◽  
...  

2020 ◽  
Vol 35 (5) ◽  
pp. 493-502
Author(s):  
F. Shahamatifard ◽  
D. Rodrigue ◽  
K. Park ◽  
S. Frikha ◽  
F. Mighri

Abstract This work describes the effect of reduced graphene oxide (RGO) addition in natural rubber (NR). Firstly, RGO was synthesized based on the improved Hummer’s method then characterized by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA) to confirm that the RGO surface contains hydroxyl, epoxy, and carboxyl functional groups to improve graphene interaction with the NR matrix. In a second step, the synthesized RGO was predispersed in NR latex using the co-coagulation technique then added at different amounts (0 to 2 parts per hundred rubber (phr)) to a basic NR formulation and compounded in an internal mixer. The results show that the crosslink density of the developed NR/RGO nanocomposites increased by 65% for RGO concentration of 2.0 phr. For the same RGO concentration, a significant increase in tensile strength (53%) and Young’s modulus (31%) were also observed. Finally, a significant improvement (26%) of the thermal conductivity was obtained with the addition of only 0.5 phr of RGO.


Polymers ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 3277
Author(s):  
Jian Wang ◽  
Baohua Liu ◽  
Yu Cheng ◽  
Zhenwan Ma ◽  
Yanhu Zhan ◽  
...  

A flexible, wearable electronic device composed of magnetic iron oxide (Fe3O4)/reduced graphene oxide/natural rubber (MGNR) composites with a segregated network was prepared by electrostatic self-assembly, latex mixing, and in situ reduction. The segregated network offers the composites higher electrical conductivity and more reliable sensing properties. Moreover, the addi-tion of Fe3O4 provides the composites with better electromagnetic interference shielding effectiveness (EMI SE). The EMI shielding property of MGNR composites is more stable under tensile deformation and long-term cycling conditions and has a higher sensitivity to stretch strain compared with the same structure made from reduced graphene oxide/natural rubber (GNR) composites. The EMI SE value of MGNR composites reduces by no more than 2.9% under different tensile permanent deformation, cyclic stretching, and cyclic bending conditions, while that of GNR composites reduces by approximately 16% in the worst case. Additionally, the MGNR composites have a better sensing performance and can maintain stable signals, even in the case of cyclic stretching with a very small strain (0.05%). Furthermore, they can steadily monitor the changes in resistance signals in various human motions such as finger bending, wrist bending, speaking, smiling, and blinking, indicating that the MGNR composites can be used in future wearable electronic flexibility devices.


ACS Omega ◽  
2019 ◽  
Vol 4 (2) ◽  
pp. 3458-3468 ◽  
Author(s):  
Antonio Capezza ◽  
Richard L. Andersson ◽  
Valter Ström ◽  
Qiong Wu ◽  
Benedetta Sacchi ◽  
...  

2017 ◽  
Vol 17 (2) ◽  
pp. 1133-1139 ◽  
Author(s):  
Chaoqun Li ◽  
Jiang Wang ◽  
Xin Chen ◽  
Yingze Song ◽  
Kangjia Jiang ◽  
...  

2019 ◽  
Vol 3 (2) ◽  
pp. 31 ◽  
Author(s):  
Hector Aguilar-Bolados ◽  
Ahirton Contreras-Cid ◽  
Andronico Neira-Carrillo ◽  
Miguel Lopez-Manchado ◽  
Mehrdad Yazdani-Pedram

Electrically conducting elastomer composites based on natural rubber and reduced graphene oxide (rGO) is reported. These composites were prepared by a latex method and an easy washing process. The latex method consists of the mixing of an aqueous suspension of rGO, stabilized by sodium dodecyl sulfate and pre-vulcanized natural rubber, followed by solvent casting. The percolation threshold of composites was estimated at 1.54 wt.% of rGO. The washing process allowed elimination of the surfactant completely from nanocomposites. The absence of surfactant in nanocomposites was demonstrated by Raman spectroscopy and dynamo-mechanical analysis. The surfactant-free nanocomposites showed improved mechanical and electrical properties.


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