High Solid-State Efficiency Fluorescent Main Chain Liquid Crystalline Polytriazoles with Aggregation-Induced Emission Characteristics

2011 ◽  
Vol 44 (24) ◽  
pp. 9618-9628 ◽  
Author(s):  
Wang Zhang Yuan ◽  
Zhen-Qiang Yu ◽  
Youhong Tang ◽  
Jacky W. Y. Lam ◽  
Ni Xie ◽  
...  
2015 ◽  
Vol 6 (22) ◽  
pp. 4167-4176 ◽  
Author(s):  
Satoshi Honda ◽  
Maito Koga ◽  
Masatoshi Tokita ◽  
Takuya Yamamoto ◽  
Yasuyuki Tezuka

The effects of the macrocyclization of amphiphiles with a liquid crystalline segment were investigated in the solid state, and electric field-responsive cylindrical micelles and vesicles were self-assembled.


2020 ◽  
Vol 59 (25) ◽  
pp. 10037-10041 ◽  
Author(s):  
Lukas Biesen ◽  
Nithiya Nirmalananthan‐Budau ◽  
Katrin Hoffmann ◽  
Ute Resch‐Genger ◽  
Thomas J. J. Müller

2015 ◽  
Vol 131 (3) ◽  
pp. 206-212
Author(s):  
Zhi-Yong Chen ◽  
Yan-Fang Ma ◽  
Ya-Ling Liu ◽  
Yi-Feng Sun ◽  
Zhen-Guo Chi

RSC Advances ◽  
2020 ◽  
Vol 10 (62) ◽  
pp. 38107-38113
Author(s):  
Kaspars Leduskrasts ◽  
Edgars Suna

Protonation of planar organic luminophores with perchloric acid turns on high solid state luminescence.


2018 ◽  
Vol 34 (4) ◽  
pp. 1741-1748 ◽  
Author(s):  
ABDULHAMID UMAR ◽  
MUSTAFFA SHAMSUDDIN

The combination of aggregation-induced emission (AIE) and liquid crystal properties generates solid-state efficient luminescent liquid crystal materials. Here in, we reported the synthesis of 1,3,5-triazine-2,4,6-tricarboxamide and utilized it as a supramolecular organic motif for the AIE-active liquid crystal material. The compound exhibits high-intensity emission maxima at 417 and 468 nm in the solid state with excitation at 254 nm, whereas it shows weak emission in the solution phase. Also, this compound behaves as liquid crystalline material and shows columnar hexagonal mesophase with endothermic peaks at 73.4oC, 185.6oC, and exothermic peaks were observed at 181.9oC and 66.1oC with focal conic fan shape texture. The thermal data showed that the compound is stable up to 200oC.


2017 ◽  
Vol 5 (4) ◽  
pp. 960-968 ◽  
Author(s):  
Bin Chen Bin Chen ◽  
Han Zhang ◽  
Wenwen Luo ◽  
Han Nie ◽  
Rongrong Hu ◽  
...  

A novel aggregation-induced emission (AIE) system with high solid-state emission efficiency is established by oxidizing thieno[3,2-b]thiophene to thieno[3,2-b]thiophene S,S-dioxide.


Author(s):  
Linda C. Sawyer

Recent liquid crystalline polymer (LCP) research has sought to define structure-property relationships of these complex new materials. The two major types of LCPs, thermotropic and lyotropic LCPs, both exhibit effects of process history on the microstructure frozen into the solid state. The high mechanical anisotropy of the molecules favors formation of complex structures. Microscopy has been used to develop an understanding of these microstructures and to describe them in a fundamental structural model. Preparation methods used include microtomy, etching, fracture and sonication for study by optical and electron microscopy techniques, which have been described for polymers. The model accounts for the macrostructures and microstructures observed in highly oriented fibers and films.Rod-like liquid crystalline polymers produce oriented materials because they have extended chain structures in the solid state. These polymers have found application as high modulus fibers and films with unique properties due to the formation of ordered solutions (lyotropic) or melts (thermotropic) which transform easily into highly oriented, extended chain structures in the solid state.


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