Origin of Initial Uncontrolled Polymerization and Its Suppression in the Copper(0)-Mediated Living Radical Polymerization of Methyl Acrylate in a Nonpolar Solvent

2011 ◽  
Vol 44 (20) ◽  
pp. 8034-8041 ◽  
Author(s):  
Andrew G. West ◽  
Ben Hornby ◽  
Jessica Tom ◽  
Vincent Ladmiral ◽  
Simon Harrisson ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
Nonpolar Solvent

scholarly journals One-pot synthesis for gradient copolymers via concurrent tandem living radical polymerization: mild and selective transesterification of methyl acrylate through Al(acac)3 with common alcohols

RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26049-26055
Author(s):  
Tam Thi-Thanh Huynh ◽  
Si Eun Kim ◽  
Soon Cheon Kim ◽  
Jin Chul Kim ◽  
Young Il Park ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
One Pot ◽  
Gradient Copolymers ◽  
One Pot Synthesis

The acrylate based gradient copolymers were successfully synthesized by concurrent tandem living radical polymerization using Al(acac)3 as cocatalyst with common alcohols.

Living radical polymerization of vinyl acetate and methyl acrylate mediated by Co(Salen*) complexes

2013 ◽  
Vol 4 (10) ◽  
pp. 3098 ◽  
Author(s):  
Chei-Ming Liao ◽  
Ching-Chun Hsu ◽  
Fu-Sheng Wang ◽  
Bradford B. Wayland ◽  
Chi-How Peng
Keyword(s):  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
Salen Complexes
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