Effects of Reactive Annealing on the Structure of Poly(methacrylic acid)–Poly(methyl methacrylate) Diblock Copolymer Thin Films

2011 ◽  
Vol 44 (16) ◽  
pp. 6525-6531 ◽  
Author(s):  
Yan Sun ◽  
Kevin J. Henderson ◽  
Zhang Jiang ◽  
Joseph W. Strzalka ◽  
Jin Wang ◽  
...  
Keyword(s):  
Thin Films ◽  
Methyl Methacrylate ◽  
Methacrylic Acid ◽  
Diblock Copolymer ◽  
Poly Methyl Methacrylate

Fabrication of Poly(methyl methacrylate)-block-Poly(methacrylic acid) Diblock Copolymer as a Self-embrittling Strippable Coating for Radioactive Decontamination

2016 ◽  
Vol 45 (7) ◽  
pp. 793-794 ◽  
Author(s):  
Ren-Long Liu ◽  
Yin-Tao Li ◽  
Yuan-Lin Zhou ◽  
Hui-Yan Zhang ◽  
Quan-Ping Zhang ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Methacrylic Acid ◽  
Diblock Copolymer ◽  
Poly Methyl Methacrylate

Synthesis of poly(methyl methacrylate)-b-poly(acrylic acid) by DPE method

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Dong Chen ◽  
Ruixue Liu ◽  
Zhifeng Fu ◽  
Yan Shi
Keyword(s):  
Molecular Weight ◽  
Acrylic Acid ◽  
Methyl Methacrylate ◽  
Diblock Copolymer ◽  
Self Assembly ◽  
Gel Permeation Chromatography ◽  
Amphiphilic Diblock Copolymer ◽  
Poly Methyl Methacrylate ◽  
Copolymer Poly ◽  
Poly Acrylic Acid

AbstractAmphiphilic diblock copolymer poly(methyl methacrylate)-b-poly(acrylic acid) (PMMA-b-PAA) was prepared by 1,1-diphenylethene (DPE) method. Firstly, free radical polymerization of methyl methacrylate was carried out with AIBN as initiator in the presence of DPE, giving a DPE-containing PMMA precursor with controlled molecular weight. tert-Butyl acrylate (tBA) was then polymerized in the presence of the PMMA precursor, and PMMA-b-PtBA diblock copolymer with controlled molecular weight was prepared. Finally, amphiphilic diblock copolymer PMMA-b-PAA was obtained by hydrolysis of PMMA-b-PtBA. The formation of PMMA-b-PAA was confirmed by 1H NMR spectrum and gel permeation chromatography. Transmission electron microscopy and dynamic light scattering were used to detect the self-assembly behavior of the amphiphilic diblock polymers in methanol.

Stereoassociation between poly(methyl methacrylate) and poly(methacrylic acid)

1975 ◽  
Vol 13 (12) ◽  
pp. 725-729 ◽  
Author(s):  
J. H. G. M. Lohmeyer ◽  
G. Kransen ◽  
Y. Y. Tan ◽  
G. Challa
Keyword(s):  
Methyl Methacrylate ◽  
Methacrylic Acid ◽  
Poly Methyl Methacrylate
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