Self-Assembly into Multicompartment Micelles and Selective Solubilization by Hydrophilic−Lipophilic−Fluorophilic Block Copolymers

2011 ◽  
Vol 44 (7) ◽  
pp. 2092-2105 ◽  
Author(s):  
Jean-Noël Marsat ◽  
Matthias Heydenreich ◽  
Erich Kleinpeter ◽  
Hans v. Berlepsch ◽  
Christoph Böttcher ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Multicompartment Micelles

Hierarchical self-assembly of a PS-b-P4VP/PS-b-PNIPAM mixture into multicompartment micelles and their response to two-dimensional confinement

2020 ◽  
Vol 22 (3) ◽  
pp. 1194-1203 ◽  
Author(s):  
Xuan Yue ◽  
Zhen Geng ◽  
Nan Yan ◽  
Wei Jiang
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Synergistic Effects ◽  
Two Dimensional ◽  
Multicompartment Micelles

Finely tuned synergistic effects among different blocks could realize intriguing hierarchical self-assembly of block copolymers and such hierarchical self-assembly could be manipulated by cylindrical confinement to tune the structures of assemblies.

Synthesis of Ternary, Hydrophilic−Lipophilic−Fluorophilic Block Copolymers by Consecutive RAFT Polymerizations and Their Self-Assembly into Multicompartment Micelles

2010 ◽  
Vol 43 (1) ◽  
pp. 271-281 ◽  
Author(s):  
Katja Skrabania ◽  
Hans v. Berlepsch ◽  
Christoph Böttcher ◽  
André Laschewsky
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Multicompartment Micelles

A DISSIPATIVE PARTICLE DYNAMICS STUDY ON THE MORPHOLOGIES OF H-SHAPED BLOCK COPOLYMERS IN SOLVENT

2011 ◽  
Vol 25 (06) ◽  
pp. 843-850
Author(s):  
XI SHAO ◽  
KAI YANG ◽  
YU-QIANG MA
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Dissipative Particle Dynamics ◽  
Particle Dynamics ◽  
The Self ◽  
Selective Solvent ◽  
Convenient Approach ◽  
Multicompartment Micelles ◽  
Dynamics Method

Multicompartment micelles have advanced applications in biological and pharmaceutical fields. The self-assembly of the block copolymers with different chain architectures provides versatile and powerful routes to obtain multicompartment micelles in water. Here we apply the dissipative particle dynamics method to study the self-assembly of H-shaped triblock copolymers in a selective solvent. It is found that the H-shaped triblock copolymers can form micelles with different morphologies, such as worm-like micelles, hamburger micelles, core-shell-corona micelles, and cylinder micelles, etc. Among them, the cylinder micelles have not been reported before in the case of the copolymers with similar chain architecture (e.g., Y-shaped copolymer). We demonstrate a convenient approach to obtain different morphologies by only adjusting the arrangement of the copolymers' blocks. These results may be helpful for the design of multicompartment micelles for various application purposes.

scholarly journals Synthesis and complex self-assembly of amphiphilic block copolymers with a branched hydrophobic poly(2-oxazoline) into multicompartment micelles, pseudo-vesicles and yolk/shell nanoparticles

2020 ◽  
Vol 11 (6) ◽  
pp. 1237-1248 ◽  
Author(s):  
Davy Daubian ◽  
Jens Gaitzsch ◽  
Wolfgang Meier
Keyword(s):  
Block Copolymers ◽  
Diblock Copolymer ◽  
Self Assembly ◽  
Amphiphilic Block Copolymers ◽  
Side Chain ◽  
Shell Nanoparticles ◽  
Amphiphilic Diblock Copolymer ◽  
Self Assembled ◽  
Multicompartment Micelles

A new PEO-b-PEHOx amphiphilic diblock copolymer was achieved which unlocked new complex self-assembled structures. Thanks to its hydrophobic oxazoline block with a long branched side chain, EHOx, various potent structures were obtained.

Self-Assembly of Hydrogels From Elastin-Mimetic Block Copolymers

2002 ◽  
Vol 724 ◽  
Author(s):  
Elizabeth R. Wright ◽  
R. Andrew McMillan ◽  
Alan Cooper ◽  
Robert P. Apkarian ◽  
Vincent P. Conticello
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Variable Temperature ◽  
Inverse Temperature ◽  
Temperature Transition ◽  
Scanning Calorimetry ◽  
Design Synthesis ◽  
Inverse Temperature Transition ◽  
Functional Biomaterials

AbstractTriblock copolymers have traditionally been synthesized with conventional organic components. However, triblock copolymers could be synthesized by the incorporation of two incompatible protein-based polymers. The polypeptides would differ in their hydrophobicity and confer unique physiochemical properties to the resultant materials. One protein-based polymer, based on a sequence of native elastin, that has been utilized in the synthesis of biomaterials is poly (Valine-Proline-Glycine-ValineGlycine) or poly(VPGVG) [1]. This polypeptide has been shown to have an inverse temperature transition that can be adjusted by non-conservative amino acid substitutions in the fourth position [2]. By combining polypeptide blocks with different inverse temperature transition values due to hydrophobicity differences, we expect to produce amphiphilic polypeptides capable of self-assembly into hydrogels. Our research examines the design, synthesis and characterization of elastin-mimetic block copolymers as functional biomaterials. The methods that are used for the characterization include variable temperature 1D and 2D High-Resolution-NMR, cryo-High Resolutions Scanning Electron Microscopy and Differential Scanning Calorimetry.

Square patterns formed from the directed self-assembly of block copolymers

2021 ◽  
Author(s):  
Weihua Li ◽  
Xueying Gu
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Bottom Up ◽  
Tremendous Progress

Since tremendous progress has been made, directed self-assembly (DSA) of block copolymers has been regarded as one of the most promising bottom-up lithography techniques. In particular, DSA has been successfully...

Effects of Trace Water on Self-Assembly of Sulfonated Block Copolymers During Solution Processing

2020 ◽  
Vol 2 (11) ◽  
pp. 4893-4901
Author(s):  
Karthika Madathil ◽  
Kayla A. Lantz ◽  
Morgan Stefik ◽  
Gila E. Stein
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Solution Processing ◽  
Trace Water

Self-Assembly of Single Chain Janus Nanoparticles from Azobenzene-Containing Block Copolymers and Reversible Photoinduced Morphology Transition

2021 ◽  
Author(s):  
Wei Wen ◽  
Aihua Chen
Keyword(s):  
Block Copolymers ◽  
Experimental Research ◽  
Self Assembly ◽  
The Self ◽  
Single Chain ◽  
Morphology Transition ◽  
Janus Nanoparticles ◽  
Assembly Behavior

Self-assembly of amphiphilic single chain Janus nanoparticles (SCJNPs) is a novel and promising approach to fabricate assemblies with diversified morphologies. However, the experimental research of the self-assembly behavior of SCJNPs...

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