Behavior of Surface-Anchored Poly(acrylic acid) Brushes with Grafting Density Gradients on Solid Substrates:  1. Experiment

2007 ◽  
Vol 40 (24) ◽  
pp. 8756-8764 ◽  
Author(s):  
Tao Wu ◽  
Peng Gong ◽  
Igal Szleifer ◽  
Petr Vlček ◽  
Vladimír Šubr ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Density Gradients ◽  
Grafting Density ◽  
Solid Substrates ◽  
Poly Acrylic Acid

Behavior of Surface-Anchored Poly(acrylic acid) Brushes with Grafting Density Gradients on Solid Substrates

2005 ◽  
pp. 287-315 ◽  
Author(s):  
Tao Wu ◽  
Jan Genzer ◽  
Peng Gong ◽  
Igal Szleifer ◽  
Petr Vlc̆ek ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Density Gradients ◽  
Grafting Density ◽  
Solid Substrates ◽  
Poly Acrylic Acid

Effect of grafting density on conformation of poly(acrylic acid) in solution by dielectric spectroscopy

Soft Matter ◽  
2018 ◽  
Vol 14 (35) ◽  
pp. 7190-7203 ◽  
Author(s):  
Xinlu Zhou ◽  
Kongshuang Zhao
Keyword(s):  
Acrylic Acid ◽  
Ethylene Oxide ◽  
Dielectric Relaxation ◽  
Dielectric Spectroscopy ◽  
Dielectric Relaxation Spectroscopy ◽  
Frequency Range ◽  
Grafting Density ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene ◽  
Poly Acrylic Acid

The effect of grafting density of poly(ethylene oxide) and dodecyl groups on the conformation of poly(acrylic acid) in solution was clarified by dielectric relaxation spectroscopy over a frequency range from 40 Hz to 110 MHz.

Soft ionic liquid based resistive memory characteristics in a two terminal discrete polydimethylsiloxane cylindrical microchannel

2020 ◽  
Vol 8 (38) ◽  
pp. 13368-13374
Author(s):  
Muhammad Umair Khan ◽  
Gul Hassan ◽  
Jinho Bae
Keyword(s):  
Ionic Liquid ◽  
Acrylic Acid ◽  
Sodium Hydroxide ◽  
Sodium Salt ◽  
Resistive Memory ◽  
Cylindrical Microchannel ◽  
Memory Characteristics ◽  
Poly Acrylic Acid

This paper proposes a novel soft ionic liquid (IL) electrically functional device that displays resistive memory characteristics using poly(acrylic acid) partial sodium salt (PAA-Na+:H2O) solution gel and sodium hydroxide (NaOH) in a thin polydimethylsiloxane (PDMS) cylindrical microchannel.

Reactions of macroions with ester and carboxylic groups of polymers

1987 ◽  
Vol 52 (9) ◽  
pp. 2194-2203
Author(s):  
Miloslav Kučera ◽  
Dušan Kimmer ◽  
Karla Majerová ◽  
Josef Majer
Keyword(s):  
Maleic Anhydride ◽  
Acrylic Acid ◽  
Methyl Methacrylate ◽  
Bond Formation ◽  
Covalent Bond ◽  
The Other ◽  
Poly Methyl Methacrylate ◽  
Other Hand ◽  
Carboxylic Groups ◽  
Poly Acrylic Acid

In the reaction of dianions with poly(methyl methacrylate), only an insignificant amount of insoluble crosslinked product is obtained. If, however, the concentration of grafting dianions approaches that of ester groups, the amount of poly(methyl methacrylate) which may thus be crosslinked becomes quite significant. Dications, too, can bring about crosslinking of only an insignificant number of poly(methyl methacrylate) chains. Carboxylic groups in poly(acrylic acid) react with dianions and dications in an anhydrous medium similarly to ester groups. On the other hand, in the presence of a cocatalytic amount of water dications are more readily bound to carboxylic groups, forming a covalent bond. The relatively highest efficiency was observed in the bond formation between dication and the poly[styrene-alt-(maleic anhydride)], both in an anhydrous medium and in the presence of H2O.

Fabrication and Characterization of Chitosan-Poly(acrylic acid) Magnetic Nanospheres

2009 ◽  
Vol 9 (2) ◽  
pp. 1287-1290 ◽  
Author(s):  
Yuqing Ge ◽  
Song Zhang ◽  
Shiying He ◽  
Yu Zhang ◽  
Ning Gu
Keyword(s):  
Acrylic Acid ◽  
Magnetic Nanospheres ◽  
Fabrication And Characterization ◽  
Poly Acrylic Acid

Synthesis, characterization, and their some chemical and biological properties of PVA/PAA/nPS hydrogel nanocomposites: Hydrogel and wound dressing

2020 ◽  
Vol 35 (3) ◽  
pp. 203-215
Author(s):  
Mehmet Emin Diken ◽  
Berna Koçer Kizilduman ◽  
Begümhan Yilmaz Kardaş ◽  
Enes Emre Doğan ◽  
Mehmet Doğan ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Acrylic Acid ◽  
Infrared Spectra ◽  
Vinyl Alcohol ◽  
Fourier Transform Infrared ◽  
Poly Vinyl Alcohol ◽  
Seed Particles ◽  
Fourier Transform Infrared Spectra ◽  
Hydrogel Nanocomposites ◽  
Poly Acrylic Acid

The nanocomposite hydrogels were prepared by dispersing of the nanopomegranate seed particles into poly(vinyl alcohol)/poly(acrylic acid) blend matrix in an aqueous medium by the solvent casting method. These hydrogels were characterized using scanning electron microscopy, Fourier transform infrared spectra, differential scanning calorimetry, and optical contact angle instruments. The nanopomegranate seed, blend, and hydrogel nanocomposites were tested for microbial activity. In addition, cytocompatibilities of these blend and hydrogel nanocomposites/composites were tested on human lymphocyte with in vitro MTS cell viability assays. Fourier transform infrared spectra revealed that esterification reaction took place among functional groups in the structure of poly(vinyl alcohol) and poly(acrylic acid). The hydrophilic properties of all hydrogels decreased with increasing nanopomegranate seed content. The mean diameters of the nanopomegranate seed particles were about 88 nm. Nanopomegranate seed particles demonstrated antibacterial properties against gram-positive bacteria, Staphylococcus aureus, and gram-negative bacteria, Escherichia coli. The lymphocyte viabilities increased after addition of nanopomegranate seeds into the polymer blend. The swelling behavior of blend and hydrogels was dependent on the cross-linking density created by the reaction between poly(vinyl alcohol)/poly(acrylic acid) blend and nanopomegranate seed. Scanning electron microscopy images were highly consistent with Fourier transform infrared spectra, differential scanning calorimetry, and antibacterial activity results.

Sign in / Sign up

Export Citation Format

Share Document