Emulsifier-Free Controlled Free-Radical Emulsion Polymerization of Styrene via RAFT Using Dibenzyltrithiocarbonate as a Chain Transfer Agent and Acrylic Acid as an Ionogenic Comonomer:  Batch and Spontaneous Phase Inversion Processes

2006 ◽  
Vol 39 (25) ◽  
pp. 8632-8638 ◽  
Author(s):  
Sébastien Fréal-Saison ◽  
Maud Save ◽  
Chuong Bui ◽  
Bernadette Charleux ◽  
Serge Magnet
Keyword(s):  
Free Radical ◽  
Acrylic Acid ◽  
Emulsion Polymerization ◽  
Phase Inversion ◽  
Chain Transfer ◽  
Chain Transfer Agent ◽  
A Chain ◽  
Spontaneous Phase

Synthesis and degradation of branched, photo-labile poly(acrylic acid) and polystyrene

2019 ◽  
Vol 10 (5) ◽  
pp. 593-602 ◽  
Author(s):  
O. Eckardt ◽  
S. Seupel ◽  
G. Festag ◽  
M. Gottschaldt ◽  
F. H. Schacher
Keyword(s):  
Free Radical ◽  
Acrylic Acid ◽  
Radical Polymerization ◽  
Chain Transfer ◽  
Free Radical Polymerization ◽  
Chain Transfer Agent ◽  
A Chain ◽  
Synthesis And Degradation ◽  
Poly Acrylic Acid

We present the synthesis, characterization and photolytical degradation of branched photo-responsive poly(acrylic acid) and polystyrene using free radical polymerization of acrylic acid/styrene in the presence of a newly synthesized asymmetric o-nitrobenzyl-based crosslinker and different amounts of dodecanethiol (DDT) as a chain transfer agent.

The effects of a chain transfer agent on the kinetics of the emulsion polymerization of styrene

1980 ◽  
Vol 18 (11) ◽  
pp. 711-716 ◽  
Author(s):  
Barry C. Y. Whang ◽  
Gottfried Lichti ◽  
Robert G. Gilbert ◽  
Donald H. Napper ◽  
David F. Sangster
Keyword(s):  
Emulsion Polymerization ◽  
Chain Transfer ◽  
Chain Transfer Agent ◽  
A Chain ◽  
Kinetics Of

Facile photo-flow synthesis of branched poly(butyl acrylate)s

2017 ◽  
Vol 2 (4) ◽  
pp. 479-486 ◽  
Author(s):  
O. Eckardt ◽  
B. Wenn ◽  
P. Biehl ◽  
T. Junkers ◽  
F. H. Schacher
Keyword(s):  
Free Radical ◽  
Propylene Glycol ◽  
Radical Polymerization ◽  
Butyl Acrylate ◽  
Chain Transfer ◽  
Free Radical Polymerization ◽  
Chain Transfer Agent ◽  
Flow Synthesis ◽  
Glycol Diacrylate ◽  
A Chain

We present the synthesis of branched poly(butyl acrylate)s using photo-induced free radical polymerization of (n/t)-butyl acrylate in the presence of tri(propylene glycol) diacrylate (TPGDA) as a crosslinker and varying amounts of dodecanethiol (DDT) as a chain transfer agent to prevent macroscopic gelation.

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